2,4,5-trinitroimidazole-based energetic salts

被引：126
作者：
Gao, Haixiang
Ye, Chengfeng
Gupta, Om D.
Xiao, Ji-Chang
Hiskey, Michael A.
Twamley, Brendan
Shreeve, Jean'ne M. [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
[3] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2007年 / 13卷 / 14期
关键词：
D O I：
10.1002/chem.200601860
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2,4,5-Trinitroimidazol ate (TNI) salts with "high-nitrogen" cations tend to be highly hydrogen bonded and have heats of formation ranging up to 616 kJ mol(-1). Density, oxygen balance, and thermostability are enhanced by the presence of TNI. Based on theoretical calculations, all of the new salts are potential propellants.
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页码：3853 / 3860
页数：8
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