A superparamagnetic metallopolymer using tailor-made poly [2-(acetoacetoxy)ethyl methacrylate] bearing pendant β-keto ester functionality

被引：10

作者：

Mandal, Prithwiraj ^{[1
,2
]}

Banerjee, Sovan Lal ^{[1
]}

Bhattacharya, Koushik ^{[1
]}

Singha, Nikhil K. ^{[1
]}

机构：

[1] Indian Inst Technol, Rubber Technol Ctr, Kharagpur 721302, W Bengal, India

[2] Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang 790784, South Korea

来源：

EUROPEAN POLYMER JOURNAL | 2018年 / 103卷

关键词：

ATRP; Acetoacetate; Metallopolymer; Superparamagnetic; beta-keto ester; METALLOSUPRAMOLECULAR POLYMERS; SUPRAMOLECULAR POLYMERS; RADICAL POLYMERIZATION; METAL-COMPLEXES; LIGAND; COPOLYMERS; BLOCK; RAFT; IONS;

D O I：

10.1016/j.eurpolymj.2018.03.024

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly [2-(acetoacetoxy)ethyl methacrylate] (PAEMA), a functional polymer bearing pendant beta-keto ester group was prepared via atom transfer radical polymerization (ATRP). The polymers were characterized by H-1 NMR, GPC and DSC analyses. H-1 NMR analysis showed that beta-keto ester group present in the side chain of the PAEMA was more in the keto form as compared to the enol form. The reactive pendant beta-keto ester group of PAEMA reacted with cobalt(II) ion to form metallopolymer which was characterized by FT-IR, UV-vis, TGA, DSC, FESEM and TEM analyses. This cobalt-polymer complex showed the formation of nanogel, as observed by DLS analysis. Importantly, this cobalt-polymer complex showed superparamagnetic behavior, as observed via superconducting quantum interference device (SQUID) analysis, indicating its potential application in magnetic fluid hyperthermia treatment and radiotherapy.

引用

页码：31 / 39

页数：9