Thermo-responsive polymer micelle-based nanoreactors for intelligent polyoxometalate catalysis

被引：10
|
作者：
Wu, Xiaowei [1 ]
Hu, Yanfang [1 ]
Wang, Xiaohong [1 ]
Chen, Li [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 58卷
基金：
中国国家自然科学基金;
关键词：
Thermo-responsive; Polyoxometalates; Smart catalysts; ORGANIC-SYNTHESIS; SYSTEM; OXIDATION; WATER;
D O I：
10.1016/j.catcom.2014.09.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of polymer micelle-based nanoreactor containing polyoxometalates and poly(N-isopropylacrylamide)block-poly(L-lysine) (PNIPAM-b-PLys-POM) have been successfully constructed. By adjusting the molar ratio of NIPAM/Lys, the temperature-depend catalytic activity of PNIPAM-b-PLys-POM towards catalytic wet hydrogen peroxide oxidation can be controlled. This work highlights the potential of using thermo-responsive micelles as a platform for developing smart catalyst system. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：164 / 168
页数：5
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