Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases

被引：103

作者：

Nickerl, Georg ^{[1
]}

Senkovska, Irena ^{[1
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01069 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 12期

关键词：

METAL-ORGANIC FRAMEWORKS; LUMINESCENT;

D O I：

10.1039/c4cc08136f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dihydro-1,2,4,5-tetrazine-3,6-dicarboxylate was introduced into the chemically stable UiO-66 structure by a postsynthetic linker exchange reaction to create an optical sensor material for the detection of oxidative agents such as nitrous gases. The incorporated tetrazine unit can be reversibly oxidized and reduced, which is accompanied by a drastic colour change from yellow to pink and vice versa. The high stability of the framework during redox reaction was proven by powder X-ray diffraction and nitrogen physisorption measurements.

引用

页码：2280 / 2282

页数：3

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