A structure-activity controllable synthesis of skeletal CuAlZn catalyst for hydrogenation of bicarbonate to formic acid in water

被引：12
作者：
Jiang, Naimeng [1 ]
Sun, Hua [2 ]
Ren, Dezhang [2 ]
Pang, Qi [1 ]
Jin, Fangming [2 ]
Huo, Zhibao [2 ]
机构：
[1] Guangxi Univ, Sch Chem & Chem Engn, 100 Daxuedong Rd, Nanning 530004, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
来源：
JOURNAL OF CO2 UTILIZATION | 2017年 / 20卷
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide; Skeletal CuAlZn catalyst; Bicarbonate; Formic acid; Green synthesis; DEFINED IRON CATALYST; CARBON-DIOXIDE; HIGHLY EFFICIENT; RANEY-NICKEL; CO2; CONVERSION; REDUCTION; CHALLENGES; METHANOL; FORMATE;
D O I：
10.1016/j.jcou.2017.05.015
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper, a structure-activity controllable synthesis of ternary skeletal CuAlZn catalyst for NaHCO3 hydrogenation to produce formic acid was first investigated. Several kinds of Cu alloy and/or the synthetic methods were considered and their catalytic activities for hydrogenation of NaHCO3 were discussed. The results found that skeletal CuAlZn-2.5 h catalyst exhibited great catalytic activity to afford the maximum value of 86.1% of formic acid with 6 MPa H-2 at 200 degrees C for 4 h. Reusability showed skeletal CuAlZn-2.5 h could still keep high catalytic activity for at least three times repeat. The present study provides an efficient and eco-friendly method for formic acid synthesis through the hydrogenation of NaHCO3 or/and CO2.
引用
收藏
页码：218 / 223
页数：6
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