Hydrogen Gas Sensor Using Pt- and Pd-Added Anodic TiO2 Nanotube Films

被引：68

作者：

Joo, Sungwook ^{[1
]}

Muto, Izumi ^{[1
]}

Hara, Nobuyoshi ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Mat Sci, Sendai, Miyagi 9808579, Japan

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2010年 / 157卷 / 06期

关键词：

SENSING PROPERTIES; H-2; FABRICATION; DIFFUSION; GROWTH; CO;

D O I：

10.1149/1.3374643

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

TiO2 nanotube films were formed on pure Ti, Ti-Pt, and Ti-Pd thin films by anodization in a mixture of glycerol and water (1: 1 volume ratio) containing 0.5 wt % NH4F and were applied as a resistance-type hydrogen gas sensor. A transmission electron microscopy analysis of the TiO2 nanotube films revealed that the nanosized particles of Pt and Pd were dispersed in the wall of the nanotube. These dispersed Pt or Pd particles effectively improved the performance of the hydrogen gas sensor perhaps due to the acceleration of hydrogen chemisorption on the wall of the nanotube. Pt- and Pd-added TiO2 nanotube sensors showed a two-order decrease in resistance upon exposure to 1000 ppm H-2 at 290 degrees C and had little or no response to 1000 ppm CH4, 1000 ppm CO, and 1 ppm SO2. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3374643] All rights reserved.

引用

页码：J221 / J226

页数：6

共 42 条

[1] BAKKER E, 2002, ANAL CHEM, V74, P3285
[2] MECHANISMS FOR HYDROGEN DIFFUSION IN TIO2
BATES, JB
WANG, JC
PERKINS, RA
[J]. PHYSICAL REVIEW B, 1979, 19 (08): : 4130 - 4139
[3] CARBON-MONOXIDE AND HYDROGEN DETECTION BY ANATASE MODIFICATION OF TITANIUM-DIOXIDE
BIRKEFELD, LD
AZAD, AM
AKBAR, SA
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (11) : 2964 - 2968
[4] A novel high-sensitive Pd/InP hydrogen sensor fabricated by electroless plating
Chen, HI
Chou, YI
Chu, CY
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 2002, 85 (1-2) : 10 - 18
[5] SOLID-STATE SENSORS FOR TRACE HYDROGEN GAS-DETECTION
CHRISTOFIDES, C
MANDELIS, A
[J]. JOURNAL OF APPLIED PHYSICS, 1990, 68 (06) : R1 - R30
[6] PRINCIPLES OF DETECTION OF FLAMMABLE ATMOSPHERES BY CATALYTIC DEVICES
FIRTH, JG
JONES, A
JONES, TA
[J]. COMBUSTION AND FLAME, 1973, 20 (03) : 303 - 311
[7] THE ROLE OF CATALYSIS IN SOLID-STATE GAS SENSORS
GENTRY, SJ
JONES, TA
[J]. SENSORS AND ACTUATORS, 1986, 10 (1-2): : 141 - 163
[8] A step on the road to Hydrogen Civilization
Goltsov, VA
Veziroglu, TN
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (7-8) : 719 - 723
[9] INTRINSIC DEFECTS OF TIO2(110) - INTERACTION WITH CHEMISORBED O2, H-2, CO, AND CO2
GOPEL, W
ROCKER, G
FEIERABEND, R
[J]. PHYSICAL REVIEW B, 1983, 28 (06): : 3427 - 3438
[10] Fiber optic sensor technology: an overview
Grattan, KTV
Sun, T
[J]. SENSORS AND ACTUATORS A-PHYSICAL, 2000, 82 (1-3) : 40 - 61

← 1 2 3 4 5 →