Synthesis of magnetic alginate beads based on magnesium ferrite (MgFe2O4) nanoparticles for removal of Sr (II) from aqueous solution: kinetic, equilibrium and thermodynamic studies

被引:20
作者
Yakout, Sobhy M. [1 ,2 ,4 ]
Hassan, Mohamed R. [3 ]
Aly, Mohamed, I [1 ,2 ]
机构
[1] Atom Energy Author, Hot Labs, PO 13759, Cairo, Egypt
[2] Atom Energy Author, Waste Management Ctr, PO 13759, Cairo, Egypt
[3] Atom Energy Author, Nucl Res Ctr, PO 13759, Cairo, Egypt
[4] King Saud Univ, Biochem Dept, POB 2455, Riyadh 11451, Saudi Arabia
关键词
adsorption; isotherm; magnetic alginate; strontium; thermodynamic study; ACTIVATED CARBON; ADSORPTION THERMODYNAMICS; P-XYLENE; NANOCOMPOSITE; SORPTION; BENZENE; TOLUENE; IONS; DYES;
D O I
10.2166/wst.2018.228
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Novel magnetic alginate beads (MagAlgbeads) have been developed by incorporation of magnesium ferrite (MgFe2O4) in alginate beads with the aim of using them in the removal of strontium from aqueous solution. MagAlgbeads were characterized by transmission electron microscopy, scanning electron microscopy, X-ray fluorescence and Fourier transform infrared spectroscopy. The adsorption of strontium onto MagAlgbeads were found to depend on pH and strontium removal increases with increasing pH until pH is 6. Strontium adsorption kinetics run through pseudo-second-order model. Thermodynamically, strontium adsorption was endothermic and spontaneous. Langmuir isotherm gave good fitting for strontium removal with adsorption capacity of 505.5 mg/g. These results proved that the prepared MagAlgbeads are very efficient material for strontium adsorption.
引用
收藏
页码:2714 / 2722
页数:9
相关论文
共 36 条
[1]   Removal of heavy metals from their aqueous solutions through adsorption onto natural polymers [J].
Abdel-Halim, E. S. ;
Al-Deyab, Salem S. .
CARBOHYDRATE POLYMERS, 2011, 84 (01) :454-458
[2]   Synthesis of amine-modified zeolitic imidazolate framework-8, ultrasound-assisted dye removal and modeling [J].
Abdi, Jafar ;
Vossoughi, Manouchehr ;
Mahmoodi, Niyaz Mohammad ;
Alemzadeh, Iran .
ULTRASONICS SONOCHEMISTRY, 2017, 39 :550-564
[3]   High performance activated carbon for benzene/toluene adsorption from industrial wastewater [J].
Asenjo, Natalia G. ;
Alvarez, Patricia ;
Granda, Marcos ;
Blanco, Clara ;
Santamaria, Ricardo ;
Menendez, Rosa .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 192 (03) :1525-1532
[4]   Synthesis of magnetic alginate beads based on Fe3O4 nanoparticles for the removal of 3-methylindole from aqueous solution using Fenton process [J].
Ben Hammouda, Samia ;
Adhoum, Nafaa ;
Monser, Lotfi .
JOURNAL OF HAZARDOUS MATERIALS, 2015, 294 :128-136
[5]   Batch and continuous adsorption of strontium by plant root tissues [J].
Chen, JP .
BIORESOURCE TECHNOLOGY, 1997, 60 (03) :185-189
[6]   Low-cost farmed shrimp shells could remove arsenic from solutions kinetically [J].
Chio, Chia-Pin ;
Lin, Ming-Chao ;
Liao, Chung-Min .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 171 (1-3) :859-864
[7]   Preparation and catalytic activity of Fe alginate gel beads for oxidative degradation of azo dyes under visible light irradiation [J].
Dong, Yongchun ;
Dong, Wenjing ;
Cao, Yanan ;
Han, Zhenbang ;
Ding, Zhizhong .
CATALYSIS TODAY, 2011, 175 (01) :346-355
[8]   Removal behavior of Babool bark (Acacia nilotica) for submicro concentrations of Hg2+ from aqueous solutions:: a radiotracer study [J].
Dubey, SS ;
Gupta, RK .
SEPARATION AND PURIFICATION TECHNOLOGY, 2005, 41 (01) :21-28
[9]   Synthesis of a novel magnetic zeolite nanocomposite for removal of Cs+ and Sr2+ from aqueous solution: Kinetic, equilibrium, and thermodynamic studies [J].
Faghihian, Hossein ;
Moayed, Mohammad ;
Firooz, Alireza ;
Iravani, Mozhgan .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2013, 393 :445-451
[10]  
Gad H. M. H., 2016, ASIAN J CHEM, V28, P385, DOI DOI 10.14233/AJCHEM.2016.19364