Preparation of Si doped molecularly imprinted TiO2 photocatalyst and its degradation to antibiotic wastewater

被引:15
作者
Guo, Jifeng [1 ]
Li, Simeng [1 ]
Duan, Liang [2 ]
Guo, Ping [1 ]
Li, Xiaojie [1 ]
Cui, Qianqian [1 ]
Wang, Hui [1 ]
Jiang, Qian [1 ]
机构
[1] Changan Univ, Educ Minist, Sch Environm Sci & Engn, Key Lab Subsurface Hydrol & Ecol Arid Areas, Xian, Peoples R China
[2] Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing, Peoples R China
基金
中国国家自然科学基金;
关键词
Molecularly imprinted photocatalyst; photocatalytic degradation; antibiotic wastewater; HYDROGEN-PRODUCTION; OXYTETRACYCLINE; REDUCTION; REMOVAL; FATE; ZNO;
D O I
10.1080/10584587.2016.1159942
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
TiO2, molecularly imprinted TiO2 (TiO2/OTC) and a novel Si doped molecularly imprinted TiO2 (TiO2/SiO2/OTC) nano photocatalytic materials were prepared by liquid phase deposition method. The products were characterized by XRD and SEM. The photocatalytic activities of the samples were evaluated by the photocatalytic degradation of oxytetracycline wastewater under a xenon lamp irradiation. The results showed that TiO2/SiO2/OTC and TiO2/OTC could improve both the photocatalytic activity and the molecular recognition ability, while the photocatalytic activities of TiO2/SiO2/OTC sample was more effective than TiO2/OTC sample with 5 times reuse. The photocatalytic activity of TiO2/SiO2/OTC photocatalyst sample had a greater improvement and its photocatalytic degradation of oxytetracycline wastewater reached 80.79% in 120 minute reaction.
引用
收藏
页码:170 / 182
页数:13
相关论文
共 24 条
[1]   Photocatalytic degradation and drug activity reduction of Chloramphenicol [J].
Chatzitakis, A. ;
Berberidou, C. ;
Paspaltsis, I. ;
Kyriakou, G. ;
Sklaviadis, T. ;
Poulios, I. .
WATER RESEARCH, 2008, 42 (1-2) :386-394
[2]   Degradation of the antibiotic oxolinic acid by photocatalysis with TiO2 in suspension [J].
Giraldo, Ana L. ;
Penuela, Gustavo A. ;
Torres-Palma, Ricardo A. ;
Pino, Nancy J. ;
Palominos, Rodrigo A. ;
Mansilla, Hector D. .
WATER RESEARCH, 2010, 44 (18) :5158-5167
[3]   Photodegradation of sodium naproxen and oxytetracycline hydrochloride in aqueous medium using as photocatalysts Mg-Al calcined hydrotalcites [J].
Jacome-Acatitla, G. ;
Tzompantzi, F. ;
Lopez-Gonzalez, R. ;
Garcia-Mendoza, C. ;
Alvaro, J. M. ;
Gomez, R. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2014, 277 :82-89
[4]   Photo-degradation of methylene blue using Ta-doped ZnO nanoparticle [J].
Kong, Ji-Zhou ;
Li, Ai-Dong ;
Li, Xiang-Yu ;
Zhai, Hai-Fa ;
Zhang, Wen-Qi ;
Gong, You-Pin ;
Li, Hui ;
Wu, Di .
JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (06) :1359-1364
[5]   Nd-doped ZnO as a multifunctional nanomaterial [J].
Kumar, Surender ;
Sahare, P. D. .
JOURNAL OF RARE EARTHS, 2012, 30 (08) :761-768
[6]   Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets [J].
Li, Qin ;
Guo, Beidou ;
Yu, Jiaguo ;
Ran, Jingrun ;
Zhang, Baohong ;
Yan, Huijuan ;
Gong, Jian Ru .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (28) :10878-10884
[7]   Enhanced photocatalysis on TiO2 nanotube arrays modified with molecularly imprinted TiO2 thin film [J].
Liu, Yutang ;
Liu, Ronghua ;
Liu, Chengbin ;
Luo, Shenglian ;
Yang, Lixia ;
Sui, Fan ;
Teng, Yarong ;
Yang, Renbin ;
Cai, Qingyun .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 182 (1-3) :912-918
[8]   Cs-Modified WO3 Photocatalyst Showing Efficient Solar Energy Conversion for O2 Production and Fe (III) Ion Reduction under Visible Light [J].
Miseki, Yugo ;
Kusama, Hitoshi ;
Sugihara, Hideki ;
Sayama, Kazuhiro .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (08) :1196-1200
[9]   Nano-sized Fe-metal catalyst on ZnO-SiO2: (photo-assisted deposition and impregnation) Synthesis routes and nanostructure characterization [J].
Mohamed, R. M. ;
Al-Rayyani, M. A. ;
Baeissa, E. S. ;
Mkhalid, I. A. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (24) :6824-6828
[10]   Spectroscopic analyses of the photocatalytic behavior of nano titanium dioxide [J].
Okasha, Aly ;
Gomaa, Fathia ;
Elhaes, Hanan ;
Morsy, Mohamed ;
El-Khodary, Sherif ;
Fakhry, Ahmed ;
Ibrahim, Medhat .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 136 :504-509