SO2 absorption/desorption performance of renewable phenol-based deep eutectic solvents

被引:39
作者
Liu, Xiaobang [1 ]
Gao, Bao [1 ]
Deng, Dongshun [1 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn, Zhejiang Prov Key Lab Biofuel, Hangzhou, Zhejiang, Peoples R China
关键词
Deep eutectic solvent; SO2; absorption; phenol; FUNCTIONALIZED IONIC LIQUIDS; TEMPERATURE MIXTURES LTTMS; CARBON-DIOXIDE; FLUE-GAS; EFFICIENT ABSORPTION; CHEMICAL ABSORPTION; REVERSIBLE CAPTURE; HIGHLY EFFICIENT; NEW-GENERATION; CO2; CAPTURE;
D O I
10.1080/01496395.2018.1446026
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Six renewable DESs prepared from choline chloride (CC) and phenols (guaiacol, GC; cardanol, CL) with molar ratios of phenols to CC of 3:1, 4:1 and 5:1 were investigated to absorb SO2 at 293.15-323.15K and 0-1.0 bar. Results showed that DESs demonstrated satisfactory SO2 absorption performance, and GC-CC (3:1) exhibited the maximum absorption capacity of 0.528g SO2 per g DES. The SO2 enriched DESs could be easily regenerated and recycled five times. Moreover, the DESs exhibited high selectivity of SO2/CO2. Present DESs seem to be promising absorbents for SO2 due to good performance.
引用
收藏
页码:2150 / 2158
页数:9
相关论文
共 50 条
[21]   Quantum Chemistry Insight into the Interactions Between Deep Eutectic Solvents and SO2 [J].
Atilhan, Mert ;
Altamash, Tausif ;
Aparicio, Santiago .
MOLECULES, 2019, 24 (16)
[22]   Functionalized imidazole-alkanolamine deep eutectic solvents with remarkable performance for low-concentration SO2 absorption [J].
Lee, Dongwook ;
Choi, Won Yong ;
Jang, Kyumin ;
Park, Jinwon ;
Yoo, Yunsung .
SEPARATION AND PURIFICATION TECHNOLOGY, 2023, 307
[23]   Acetylcholine-based deep eutectic solvents for highly efficient SO2 absorption, selective separation from CO2 and their mechanism [J].
Lu, Ruizhong ;
Ma, Songqi ;
Zhai, Yang ;
Geng, Zeyu ;
Jin, Zhi ;
Fu, Yong ;
Wang, Wei ;
Xu, Yun .
JOURNAL OF MOLECULAR LIQUIDS, 2023, 383
[24]   Efficient and remarkable SO2 capture: A discovery of imidazole-based ternary deep eutectic solvents [J].
Zhu, Qian ;
Wang, Chao ;
Yin, Jie ;
Li, Hongping ;
Jiang, Wei ;
Liu, Jixing ;
Li, Peipei ;
Zhang, Qi ;
Chen, Zhigang ;
Zhu, Wenshuai .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 330
[25]   High-Efficiency Absorption of SO2 by a New Type of Deep Eutectic Solvents [J].
Sheng, Kai ;
Kang, Yong ;
Li, Jie ;
Xu, Hongyang ;
Li, Dan .
ENERGY & FUELS, 2020, 34 (03) :3440-3448
[26]   Investigation of Highly Efficient and Reversible Absorption of SO2 Using Ternary Functional Deep Eutectic Solvents [J].
Hou, Shuai ;
Zhang, Congcong ;
Jiang, Bin ;
Zhang, Haiming ;
Zhang, Luhong ;
Yang, Na ;
Zhang, Na ;
Xiao, Xiaoming ;
Tantai, Xiaowei .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (43) :16241-16251
[27]   Phenol-Based Ternary Deep Eutectic Solvents for Highly Efficient and Reversible Absorption of NH3 [J].
Zhong, Fu-Yu ;
Peng, Hai-Long ;
Tao, Duan-Jian ;
Wu, Ping-Keng ;
Fan, Jie-Ping ;
Huang, Kuan .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (03) :3258-3266
[28]   Unexpectedly efficient SO2 capture and conversion to sulfur in novel imidazole-based deep eutectic solvents [J].
Zhao, Tianxiang ;
Liang, Jian ;
Zhang, Yating ;
Wu, Youting ;
Hu, Xingbang .
CHEMICAL COMMUNICATIONS, 2018, 54 (65) :8964-8967
[29]   Bisazole-Based Deep Eutectic Solvents for Efficient SO2 Absorption and Conversion without Any Additives [J].
Long, Guangcai ;
Yang, Chunliang ;
Yang, Xiaoqing ;
Zhao, Tianxiang ;
Liu, Fei ;
Cao, Jianxin .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (07) :2608-2613
[30]   Efficient absorption of low pressure NH3 by non-ionic phenol-based deep eutectic solvents with multiple acidic sites [J].
Zhou, Ziyue ;
Cao, Yu ;
Zong, Kai ;
Deng, Dongshun .
JOURNAL OF MOLECULAR LIQUIDS, 2023, 389