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SO2 absorption/desorption performance of renewable phenol-based deep eutectic solvents
被引:39
作者:
Liu, Xiaobang
[1
]
Gao, Bao
[1
]
Deng, Dongshun
[1
]
机构:
[1] Zhejiang Univ Technol, Coll Chem Engn, Zhejiang Prov Key Lab Biofuel, Hangzhou, Zhejiang, Peoples R China
关键词:
Deep eutectic solvent;
SO2;
absorption;
phenol;
FUNCTIONALIZED IONIC LIQUIDS;
TEMPERATURE MIXTURES LTTMS;
CARBON-DIOXIDE;
FLUE-GAS;
EFFICIENT ABSORPTION;
CHEMICAL ABSORPTION;
REVERSIBLE CAPTURE;
HIGHLY EFFICIENT;
NEW-GENERATION;
CO2;
CAPTURE;
D O I:
10.1080/01496395.2018.1446026
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Six renewable DESs prepared from choline chloride (CC) and phenols (guaiacol, GC; cardanol, CL) with molar ratios of phenols to CC of 3:1, 4:1 and 5:1 were investigated to absorb SO2 at 293.15-323.15K and 0-1.0 bar. Results showed that DESs demonstrated satisfactory SO2 absorption performance, and GC-CC (3:1) exhibited the maximum absorption capacity of 0.528g SO2 per g DES. The SO2 enriched DESs could be easily regenerated and recycled five times. Moreover, the DESs exhibited high selectivity of SO2/CO2. Present DESs seem to be promising absorbents for SO2 due to good performance.
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页码:2150 / 2158
页数:9
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