Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel

被引：355
|
作者：
Boekhoven, Job [1 ]
Brizard, Aurelie M. [1 ]
Kowlgi, Krishna N. K. [1 ]
Koper, Ger J. M. [1 ]
Eelkema, Rienk [1 ]
van Esch, Jan H. [1 ]
机构：
[1] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 28期
关键词：
aggregation; gels; hydrolysis; non-equilibrium processes; self-assembly; MICROSCALE OBJECTS; DRIVEN; NANOSTRUCTURES; CHEMISTRY; MOTOR; GEL; SURFACTANTS; DERIVATIVES; GENERATION; INTERFACE;
D O I：
10.1002/anie.201001511
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Fueling the future: A fibrillar network (red fibers, see figure) is formed from an activated building block (red), which is obtained from a synthetic gelator (blue) in a dissipative self-assembly process that is fueled by an alkylating agent. When the available energy is depleted, the system reverts to its thermodynamic equilibrium, that is, an isotropic solution. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4825 / 4828
页数：4
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