Mononuclear, polynuclear, and cluster complexes of molybdenum and their reactions as models of biochemical systems and processes

被引：18

作者：

Dement'ev, I. A. ^{[1
]}

Kozin, A. O. ^{[1
]}

Kondrat'ev, Yu. V. ^{[1
]}

Korol'kov, D. V. ^{[1
]}

Proyavkin, A. A. ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 198504, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 05期

关键词：

D O I：

10.1134/S1070363207050040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Data on the composition, structure, and properties (electronic and geometric structure, optical properties, thermodynamic functions) of mononuclear, polynuclear, and cluster complexes of bi-, tri-, tetra-, penta-, and hexavalent molybdenum are summarized and correlated. The thermodynamics, kinetics, and mechanisms of the ligand exchange, protonation-deprotonation, redox reactions, and formation-decomposition of cluster cores of molybdenum complexes in aqueous solutions are characterized.

引用

页码：822 / 843

页数：22

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