Reforming of ethanol in a microwave surface-wave plasma discharge

被引:72
作者
Yanguas-Gil, A [1 ]
Hueso, JL
Cotrino, J
Caballero, A
González-Elipe, AR
机构
[1] Univ Sevilla, CSIC, Inst Ciencia Mat Sevilla, Seville, Spain
[2] Univ Sevilla, CSIC, Dpto Fis Atom Mol & Nucl, Seville, Spain
[3] Univ Sevilla, CSIC, Dpto Quim Inorgan, Seville, Spain
关键词
D O I
10.1063/1.1808875
中图分类号
O59 [应用物理学];
学科分类号
摘要
Hydrogen production through plasma reforming of ethanol at room temperature and moderate pressure has been carried out in a microwave surface-wave reactor. Both pure ethanol and mixtures ethanol-water have been studied. The reforming yield was almost 100% in all conditions with H-2, solid carbon, CO and CO2 as the main reaction products. In the mixture ethanol-water the formation of solid C was avoided. The optical emission spectroscopy analysis has shown that the formation of the excited species CO*, CH* and C-2* depends on the plasma mixture. The temperature of the OH* species was determined by analyzing the shape profile of its emission band. (C) 2004 American Institute of Physics.
引用
收藏
页码:4004 / 4006
页数:3
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