Ceramic joining through reactive wetting of alumina with calcium aluminate refractory cements

被引:24
作者
Geetha, K [1 ]
Umarji, AM [1 ]
Kutty, TRN [1 ]
机构
[1] Indian Inst Sci, Mat Res Ctr, Bangalore 560012, Karnataka, India
关键词
G -> C conversion; reaction bonding; alumina ceramics; calcium aluminate; high temperature cements;
D O I
10.1007/BF02720077
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Compositions in CaO-Al2O3 system have been prepared by gel-to-crystallite conversion method. Reactive powders of 1 : 2, 1 : 1, 2: 1 and 3 : 1 of CaO and Al2O3 compositions were obtained by calcining the product at 800-1200 degrees C. Fine grained powders were used as refractory cement for joining alumina ceramics. An optimum temperature of 1450 degrees C for 4 h produced joints of satisfactory strength. The microstructure and X-ray phase analysis of the fractured joint surface clearly indicate reactive wetting of the alumina ceramics. This wetting enhances the joining of alumina substrates and can be attributed to the formation of Ca12Al14O33 liquid phase. The results are explained by using CaO-Al2O3 phase diagram.
引用
收藏
页码:243 / 248
页数:6
相关论文
共 14 条
[1]  
BATES CH, 1990, AM CERAM SOC BULL, V69, P350
[2]  
FERNIE JA, 1997, CERAMIC T, V77, P3
[3]   Influence of the preparative conditions on the precursor phases formed during the synthesis of beta-alumina by the wet chemical gel to crystallite conversions [J].
Jayaraman, V ;
Periaswami, G ;
Kutty, TRN .
MATERIALS CHEMISTRY AND PHYSICS, 1998, 52 (01) :46-53
[4]   MECHANISM OF BATIO3 FORMATION THROUGH GEL-TO-CRYSTALLITE CONVERSIONS [J].
KUTTY, TRN ;
PADMINI, P .
MATERIALS CHEMISTRY AND PHYSICS, 1995, 39 (03) :200-208
[5]   Synthesis of beta alumina from aluminum hydroxide precursor formed by gel to crystallite conversions [J].
Kutty, TRN ;
Jayaraman, V ;
Periaswami, G .
MATERIALS RESEARCH BULLETIN, 1996, 31 (09) :1159-1168
[6]   WET CHEMICAL FORMATION OF NANOPARTICLES OF BINARY PEROVSKITES THROUGH ISOTHERMAL GEL TO CRYSTALLITE CONVERSION [J].
KUTTY, TRN ;
PADMINI, P .
MATERIALS RESEARCH BULLETIN, 1992, 27 (08) :945-952
[7]  
LOEMAN RE, 1988, CERAM B, V67, P375
[8]   CERAMIC CERAMIC SEALS BY MICROWAVE-HEATING [J].
MEEK, TT ;
BLAKE, RD .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1986, 5 (03) :270-274
[9]   Large range of nonstoichiometry in barium ortho aluminate prepared through gel-to-crystallite conversion [J].
Nayak, M ;
Kutty, TRN .
MATERIALS RESEARCH BULLETIN, 1996, 31 (02) :227-234
[10]   WET CHEMICAL SYNTHESES OF ULTRAFINE MULTICOMPONENT CERAMIC POWDERS THROUGH GEL TO CRYSTALLITE CONVERSION [J].
PADMINI, P ;
KUTTY, TRN .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (12) :1875-1881