Fluorescence Properties and Density Functional Theory Calculation of a Structurally Characterized Heterotetranuclear [ZnII2-SmIII2] 4,4′-Bipy-Salamo-Constructed Complex

被引：57

作者：

An, Xiao-Xin ^{[1
]}

Liu, Chang ^{[1
]}

Chen, Zhuang-Zhuang ^{[1
]}

Xie, Ke-Feng ^{[1
]}

Zhang, Yang ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

CRYSTALS | 2019年 / 9卷 / 11期

基金：

中国国家自然科学基金;

关键词：

unsymmetrical salamo-like ligand; heterotetranuclear complex; crystal structure; fluorescence property; DFT calculation; DNA-BINDING PROPERTIES; SCHIFF-BASE; CRYSTAL-STRUCTURES; ZN-II; ELECTROCHEMICAL PROPERTIES; SUPRAMOLECULAR STRUCTURES; SPECTROSCOPIC PROPERTIES; NICKEL(II) COMPLEXES; ZINC(II) COMPLEXES; HIRSHFELD ANALYSES;

D O I：

10.3390/cryst9110602

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new heterotetranuclear complex, [{Zn(L)Sm(NO3)(3)}(2)(4,4'-bipy)]center dot 2CH(3)OH, was synthesized via an unsymmetrical single salamo-like ligand H2L: 6-methoxy-6'-ethoxy-2,2'-[ethylenedioxybis(azinomethyl)]diphenol, with Zn(OAc)(2)center dot 2H(2)O, Sm(NO3)(3)center dot 6H(2)O, and 4,4'-bipyridine by the one-pot method. The [Zn-2(II)-Sm-2(III)] complex was validated via elemental analysis, powder X-ray diffraction (PXRD) analysis, infrared spectroscopy, and ultraviolet-visible (UV-Vis) absorption spectroscopy. The X-ray single crystal diffraction analysis of the [Zn-2(II)-Sm-2(III)] complex was carried out via X-ray single-crystal crystallography. The crystal structure and supramolecular features were discussed. In addition, while studying the fluorescence properties of the [Zn-2(II)-Sm-2(III)] complex, the density functional theory (DFT) calculation of its structure was also performed.

引用

页数：16

共 73 条

[1] Guest-dependent inversion rate of a tetranuclear single metallohelicate [J].

Akine, Shigehisa ;

Taniguchi, Takanori ;

Matsumoto, Takashi ;

Nabeshima, Tatsuya .

CHEMICAL COMMUNICATIONS, 2006, (47) :4961-4963

[2] Cage-like tris(salen)-type metallocryptand for cooperative guest recognition [J].

Akine, Shigehisa ;

Piao, Shunjin ;

Miyashita, Masato ;

Nabeshima, Tatsuya .

TETRAHEDRON LETTERS, 2013, 54 (48) :6541-6544

[3] A Molecular Leverage for Helicity Control and Helix Inversion [J].

Akine, Shigehisa ;

Hotate, Sayaka ;

Nabeshima, Tatsuya .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (35) :13868-13871

[4] Synthesis of acyclic tetrakis- and pentakis(N2O2) ligands for single-helical heterometallic complexes with a greater number of winding turns [J].

Akine, Shigehisa ;

Matsumoto, Takashi ;

Sairenji, Shiho ;

Nabeshima, Tatsuya .

SUPRAMOLECULAR CHEMISTRY, 2011, 23 (1-2) :106-112

[5] Dinuclear Complexes of the N2O2 Oxime Chelate Ligand with Zinc(II)-Lanthanide(III) as a Selective Sensitization System for Sm3+ [J].

Akine, Shigehisa ;

Utsuno, Fumihiko ;

Taniguchi, Takanori ;

Nabeshima, Tatsuya .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (20) :3143-3152

[6] Cyclic and acyclic oligo(N2O2) ligands for cooperative multi-metal complexation [J].

Akine, Shigehisa ;

Nabeshima, Tatsuya .

DALTON TRANSACTIONS, 2009, (47) :10395-10408

[7] Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands: Synthesis, Crystal Structures, and Catalytic Activity [J].

Amirkhanov, Oleksiy V. ;

Moroz, Olesia V. ;

Znovjyak, Kateryna O. ;

Sliva, Tetiana Yu. ;

Penkova, Larysa V. ;

Yushchenko, Tetyana ;

Szyrwiel, Lukasz ;

Konovalova, Irina S. ;

Dyakonenko, Viktoriya V. ;

Shishkin, Oleg V. ;

Amirkhanov, Vladimir M. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (23) :3720-3730

[8] A New Half-Salamo-Based Homo-Trinuclear Nickel(II) Complex: Crystal Structure, Hirshfeld Surface Analysis, and Fluorescence Properties [J].

An, Xiao-Xin ;

Zhao, Qing ;

Mu, Hao-Ran ;

Dong, Wen-Kui .

CRYSTALS, 2019, 9 (02)

[9] Oligonuclear complexes as tectons in crystal engineering: structural diversity and magnetic properties [J].

Andruh, Marius .

CHEMICAL COMMUNICATIONS, 2007, (25) :2565-2577

[10] Incorporation of fluorescent quantum dots for 3D printing and additive manufacturing applications [J].

Brubaker, Cole D. ;

Frecker, Talitha M. ;

McBride, James R. ;

Reid, Kemar R. ;

Jennings, G. Kane ;

Rosenthal, Sandra J. ;

Adams, Douglas E. .

JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (28) :7584-7593

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