Preparation and characterization of nanoscale lutetium aluminium garnet (LuAG) powders doped by Eu3+

被引:36
作者
Uhlich, Dominik
Huppertz, P.
Wiechert, D. U.
Juestel, Thomas
机构
[1] Univ Appl Sci Munster, FB Chemieingenieurwesen, D-48565 Steinfurt, Germany
[2] Philips Res Labs, D-52066 Aachen, Germany
关键词
co-precipitation; lutetium aluminum garnet (LuAG); nanoscale particles; rare earth doping; optical properties;
D O I
10.1016/j.optmat.2006.07.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanoscale powders of Lu3Al5O12:Eu were synthesized by a standard precipitation process using (NH4)HCO3. Characterisation of the nanocrystalline particles was done with respect to particle morphology and luminescence spectra. The mean particle diameter was reduced by means of a dispersing additive during the precipitation process. A procedure was developed to gain particles in the particle size range of 20-50 mn. Additionally, the reactivity of the precipitated precursor could be enhanced to such an extent that phase transformation into the garnet phase takes place at 900 degrees C. The optical properties of the doped nanoscale lutetium garnet are identical with microscale powders. Eu3+ doped nanoscale lutetium garnet showed quantum efficiencies up to 40%. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1505 / 1509
页数:5
相关论文
共 15 条
[1]   Variation of fluorescence lifetimes and Judd-Ofelt parameters between Eu3+ doped bulk and nanocrystalline cubic LU2O3 [J].
Boyer, JC ;
Vetrone, F ;
Capobianco, JA ;
Speghini, A ;
Bettinelli, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :20137-20143
[2]   Luminescent and morphological studies of Tm-doped Lu3Al5O12 and Y3Al5O12 fine powders for scintillator detector application [J].
Cicillini, SA ;
Pires, AM ;
Serra, OA .
JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 374 (1-2) :169-172
[3]   OXYGEN COORDINATES OF COMPOUNDS WITH GARNET STRUCTURE [J].
EULER, F ;
BRUCE, JA .
ACTA CRYSTALLOGRAPHICA, 1965, 19 :971-&
[4]   Synthesis and luminescent properties of nano-sized Y3Al5O12:Eu3+ phosphors [J].
Hsu, WT ;
Wu, WH ;
Lu, CH .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 104 (1-2) :40-44
[5]  
HUHEEY JE, 1988, ANORGANISCHE CHEM PR, P78
[6]  
ITOH S, 2000, INF DISP S, V1, P187
[7]  
Jüstel T, 2001, J LUMIN, V93, P179, DOI 10.1016/S0022-2313(01)00199-5
[8]  
Li JG, 2000, J AM CERAM SOC, V83, P961
[9]   Transparent lutetium aluminum garnet sintered from carbonate coprecipitated powders [J].
Liao, YK ;
Jiang, DY ;
Shi, JL .
MATERIALS LETTERS, 2005, 59 (28) :3724-3727
[10]   Neodymium doped yttrium aluminum garnet (Y3Al5O12) nanocrystalline ceramics -: a new generation of solid state laser and optical materials [J].
Lu, JR ;
Ueda, K ;
Yagi, H ;
Yanagitani, T ;
Akiyama, Y ;
Kaminskii, AA .
JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 341 (1-2) :220-225