Investigations on the system Bi2O3/BiI3

被引:28
|
作者
Schmidt, M
Oppermann, H
Bruckner, H
Binnewies, M
机构
[1] Tech Univ Dresden, Inst Anorgan Chem, D-11069 Dresden, Germany
[2] Univ Hannover, Inst Anorgan Chem, D-3000 Hannover, Germany
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 12期
关键词
bismutoxideiodides; total pressure measurements; mass spectrometry; thermodynamic data; melting diagram; barogram;
D O I
10.1002/zaac.19976231219
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The temperature functions of decomposition pressures of the ternary compounds on the quasibinary line Bi2O3/BiI3 were determined by total pressure measurements and mass spectrometry. The barogram of the system was constructed and the melting diagram precised. The enthalpies of formation and the standard entropies of the solid phases were derived from the decomposition functions: (Values see Inhaltsubersicht).
引用
收藏
页码:1945 / 1953
页数:9
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