Synthesis, Crystal Structure and Magnetic Properties of Heptanuclear Manganese Complexes with Schiff-base Ligand

被引：0

作者：

Yang Li-Guo ^{[1
]}

Wang Xin ^{[1
]}

Yu Zhi-Chao ^{[1
]}

Zhang Yong-Hui ^{[1
]}

Li Shu-Li ^{[1
]}

Wang Kai ^{[1
]}

Niu Yong-Sheng ^{[1
]}

Song Hai-Xiang ^{[1
]}

机构：

[1] Anyang Inst Technol, Coll Chem & Environm Engn, Anyang 455000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 38卷 / 12期

关键词：

manganese; schiff base; crystal structures; magnetic properties; CARBOXYLATE CHEMISTRY; CLUSTER; FAMILY;

D O I：

10.14102/j.cnki.0254-5861.2011-2379

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One new mixed-valence heptanuclear manganese complex, [(MnMn6O2L6)-Mn-II-O-III- (NaCH3COO)(2)(CH3COO)(4)](1) (L = 3-ethoxy-6-(((2-hydroxyethyl)imino)methyl) phenol, was synthesized by treating the Schiff-base ligand with Mn(acac)(3)center dot 4H(2)O and characterized by elemental analysis, IR spectra, thermogravimetric analyses and X-ray single-crystal diffraction. 1 has a similar new mixed-valence heptanuclear structure. The magnetic measurements indicate that 1 exhibits the antiferromagnetic interactions.

引用

页码：2135 / 2140

页数：6

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