Formation constants of complexes of monovalent cations with benzocrown ethers in nitromethane

被引：11
|
作者：
Inerowicz, HD [1 ]
Chojnacki, J
Merz, A
Futterer, T
机构：
[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland
[2] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2000年 / 38卷 / 1-4期
关键词：
formation constants; stilbene crown ethers; conductometric titration; alkali metal cations; silver cation; nitromethane;
D O I：
10.1023/A:1008145406568
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complexation reactions between the macrocyclic polyethers dibenzo-18-crown-6, benzo-18-crown-6, benzo-15-crown-5 and polyethers bearing a stilbene unit with alkali metal and silver cations have been studied conductometrically in nitromethane. The formation constants of 1 : 1 and 1 : 2 (metal : ligand) complexes were determined and found to decrease with increasing cation diameter. The stability of the stilbene crown - metal cation complexes is lower than for complexes of other investigated crown ethers with analogous cations. There seem to be some effects of double bond-silver ion interactions.
引用
收藏
页码：123 / 132
页数：10
相关论文
共 50 条
  • [1] Formation Constants of Complexes of Monovalent Cations with Benzocrown Ethers in Nitromethane
    H. D. Inerowicz
    J. Chojnacki
    A. Merz
    T. Futterer
    Journal of inclusion phenomena and macrocyclic chemistry, 2000, 38 : 123 - 132
  • [2] Formation constants of complexes of monovalent cations with benzocrown ethers in nitromethane
    Inerowicz, H.D.
    Chojnacki, J.
    Merz, A.
    Futterer, T.
    2000, Springer Netherlands (38): : 1 - 4
  • [3] THE APPARENT STABILITY CONSTANTS OF IONIC COMPLEXES OF VARIOUS ADENOSINE PHOSPHATES WITH MONOVALENT CATIONS
    SMITH, RM
    ALBERTY, RA
    JOURNAL OF PHYSICAL CHEMISTRY, 1956, 60 (02): : 180 - 184
  • [4] ELECTROCHEMICAL AND INFRARED EVALUATION OF FORMATION CONSTANTS OF AQUO-COPPER(II) COMPLEXES IN NITROMETHANE
    LARSON, RC
    IWAMOTO, RT
    INORGANIC CHEMISTRY, 1962, 1 (02) : 316 - &
  • [5] INTERDEPENDENCE OF ALANINE FORMATION ON MONOVALENT AND BIVALENT CATIONS
    MACEJOVA, E
    ORLICKY, J
    RUSCAK, M
    PHYSIOLOGIA BOHEMOSLOVACA, 1969, 18 (5-6): : 498 - &
  • [6] Molecular clips based on diphenylglycoluril and benzocrown ethers: promising complexing agents for the alkali metal cations
    Kikot', Leonid S.
    Lyapunov, Alexander Yu.
    Kulygina, Catherine Yu.
    Bogaschenko, Tatiana Yu.
    Zubatyuk, Roman I.
    Shishkin, Oleg V.
    Kirichenko, Tatiana I.
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2014, 79 (3-4) : 343 - 348
  • [7] Molecular clips based on diphenylglycoluril and benzocrown ethers: promising complexing agents for the alkali metal cations
    Leonid S. Kikot’
    Alexander Yu. Lyapunov
    Catherine Yu. Kulygina
    Tatiana Yu. Bogaschenko
    Roman I. Zubatyuk
    Oleg V. Shishkin
    Tatiana I. Kirichenko
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2014, 79 : 343 - 348
  • [8] NEW APPLICATIONS OF CROWN ETHERS .6. STRUCTURAL EFFECTS OF BIS(BENZOCROWN ETHER)S AND SUBSTITUTED BENZOCROWN ETHERS ON SOLVENT-EXTRACTION AND COMPLEXATION OF ALKALI-METAL CATIONS
    KIKUKAWA, K
    HE, GX
    ABE, A
    GOTO, T
    ARATA, R
    IKEDA, T
    WADA, F
    MATSUDA, T
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (02): : 135 - 141
  • [9] HYDROLYSIS OF CATIONS - FORMATION-CONSTANTS AND STANDARD FREE-ENERGIES OF FORMATION OF HYDROXY COMPLEXES
    BARNUM, DW
    INORGANIC CHEMISTRY, 1983, 22 (16) : 2297 - 2305
  • [10] FORMATION OF 2-1 COMPLEXES BETWEEN ALKYLAMMONIUM CATIONS AND DIAZA CROWN ETHERS
    BOVILL, MJ
    CHADWICK, DJ
    JOHNSON, MR
    JONES, NF
    SUTHERLAND, IO
    NEWTON, RF
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (23) : 1065 - 1066
12345