Improved solar cell performance by adding ultra-thin Alq3 at the cathode interface

被引:11
作者
Lee, Jae Yong [1 ]
Lee, Taehwa [2 ]
Park, Hui Joon [3 ]
Guo, L. Jay [1 ,2 ]
机构
[1] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Mech Engn, Ann Arbor, MI 48109 USA
[3] Ajou Univ, Suwon 441749, South Korea
关键词
Solar cells; Cathode interface; Contact resistance; Hybrid photovoltaic; EFFICIENT;
D O I
10.1016/j.orgel.2014.08.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a new finding that ultra-thin Tris(8-hydroxyquinoline) aluminum (Alq(3)) improves an Al cathode interface for photovoltaic (PV) with inorganic amorphous silicon (a-Si) as well as organic bulk heterojunction (BHJ) photoactive layers. Contact resistance characterization is used to investigate the effect of the added Alq(3). The experimental results show that the inserted Alq3 is observed to reduce the contact resistance at the cathode interface. Supported by our numerical analysis, the enhanced cathode interface by Alq(3) provides better Ohmic contact, thereby increasing V-oc. The overall power efficiency is enhanced accordingly benefited by the Alq(3) added cathode regardless of photoactive layers. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:2710 / 2714
页数:5
相关论文
共 21 条
[1]   Interface-limited injection in amorphous organic semiconductors [J].
Baldo, MA ;
Forrest, SR .
PHYSICAL REVIEW B, 2001, 64 (08)
[2]   Effect of LiF/metal electrodes on the performance of plastic solar cells [J].
Brabec, CJ ;
Shaheen, SE ;
Winder, C ;
Sariciftci, NS ;
Denk, P .
APPLIED PHYSICS LETTERS, 2002, 80 (07) :1288-1290
[3]   Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].
Dennler, Gilles ;
Scharber, Markus C. ;
Brabec, Christoph J. .
ADVANCED MATERIALS, 2009, 21 (13) :1323-1338
[4]   Molecular level alignment at organic semiconductor-metal interfaces [J].
Hill, IG ;
Rajagopal, A ;
Kahn, A ;
Hu, Y .
APPLIED PHYSICS LETTERS, 1998, 73 (05) :662-664
[5]   Improved Performance of Polymer Bulk Heterojunction Solar Cells Through the Reduction of Phase Separation via Solvent Additives [J].
Hoven, Corey V. ;
Dang, Xuan-Dung ;
Coffin, Robert C. ;
Peet, Jeff ;
Nguyen, Thuc-Quyen ;
Bazan, Guillermo C. .
ADVANCED MATERIALS, 2010, 22 (08) :E63-+
[6]   Enhanced electron injection in organic electroluminescence devices using an Al/LiF electrode [J].
Hung, LS ;
Tang, CW ;
Mason, MG .
APPLIED PHYSICS LETTERS, 1997, 70 (02) :152-154
[7]   Sensitivity of the Mott-Schottky Analysis in Organic Solar Cells [J].
Kirchartz, Thomas ;
Gong, Wei ;
Hawks, Steven A. ;
Agostinelli, Tiziano ;
MacKenzie, Roderick C. I. ;
Yang, Yang ;
Nelson, Jenny .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (14) :7672-7680
[8]   Biased internal potential distributions in a bulk-heterojunction organic solar cell incorporated with a TiOx interlayer [J].
Kong, Jaemin ;
Lee, Jongjin ;
Jeong, Yonkil ;
Kim, Maengjun ;
Kang, Sung-Oong ;
Lee, Kwanghee .
APPLIED PHYSICS LETTERS, 2012, 100 (21)
[9]   High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].
Li, G ;
Shrotriya, V ;
Huang, JS ;
Yao, Y ;
Moriarty, T ;
Emery, K ;
Yang, Y .
NATURE MATERIALS, 2005, 4 (11) :864-868
[10]   Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology [J].
Ma, WL ;
Yang, CY ;
Gong, X ;
Lee, K ;
Heeger, AJ .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1617-1622