All-Cellulose Composites by Partial Dissolution of Cotton Fibres

被引:19
作者
Arevalo, Raquel [1 ,2 ]
Picot, Olivier T. [1 ,2 ]
Wilson, Rory M. [1 ,2 ]
Soykeabkaew, Nattakan [1 ,2 ,3 ]
Peijs, Ton [1 ,2 ,4 ]
机构
[1] Queen Mary Univ London, Sch Mat Sci & Engn, London E1 4NS, England
[2] Queen Mary Univ London, Ctr Mat Res, London E1 4NS, England
[3] Mae Fah Luang Univ, Sch Sci, Chiang Rai 57100, Thailand
[4] Eindhoven Univ Technol, Eindhoven Polymer Labs, NL-5600 MB Eindhoven, Netherlands
关键词
Self-Reinforced Polymer; All-Cellulose; DMAc; Surface Dissolution; Cotton; MOLECULAR-WEIGHT CHARACTERIZATION; LITHIUM-CHLORIDE; FLAX FIBERS; SOLVENT EXCHANGE; PARTIAL OXYPROPYLATION; MECHANICAL-PROPERTIES; VOLUME FRACTION; POLYPROPYLENE; NANOCOMPOSITES; BEHAVIOR;
D O I
10.1166/jbmb.2010.1077
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this work isotropic 'self-reinforced cellulose' or 'all-cellulose' composites have been successfully prepared from cotton pads by means of a fibre surface dissolution method in lithium chloride dissolved in N, N-dimethylacetamide (LiCl/DMAc). Solvent exchange was used as activation pretreatment, involving subsequent immersion of the fibres in water, acetone and DMAc. Three different parameters have been studied: (i) dissolution time, (ii) activation time and (iii) cotton source. The morphological, thermal and mechanical properties of the obtained all-cellulose composites were characterized. It was found that a dissolution time of 18 h lead to biobased materials with the best overall mechanical performance, as this time allowed for the dissolution of a sufficient amount of fibre surface to obtain good interfacial bonding between fibres, while keeping a considerable amount of remaining fibre cores that provide a strong reinforcement to the composite.
引用
收藏
页码:129 / 138
页数:10
相关论文
共 50 条
[41]   Preparation of C/C-SiC Composites from All-Cellulose Precursors [J].
Schneck, Tanja K. ;
Mueller, Alexandra ;
Hermanutz, Frank ;
Buchmeiser, Michael R. .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2019, 304 (04)
[42]   Water and Oxygen Barrier Properties of All-Cellulose Nanocomposites [J].
Rader, Chris ;
Grillo, Luca ;
Weder, Christoph .
BIOMACROMOLECULES, 2024, 25 (03) :1906-1915
[43]   Biodegradability of all-cellulose composite laminates [J].
Kalka, Sebastian ;
Huber, Tim ;
Steinberg, Julius ;
Baronian, Keith ;
Muessig, Joerg ;
Staiger, Mark P. .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2014, 59 :37-44
[44]   Magnetic alignment of cellulose nanowhiskers in an all-cellulose composite [J].
Dongsheng Li ;
Zuyan Liu ;
Marwan Al-Haik ;
Mehran Tehrani ;
Frank Murray ;
Rina Tannenbaum ;
Hamid Garmestani .
Polymer Bulletin, 2010, 65 :635-642
[45]   All-cellulose composite aerogels and cryogels [J].
Korhonen, Oona ;
Budtova, Tatiana .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2020, 137
[46]   Low-Density All-Cellulose Composites Made from Cotton Textile Waste with Promising Thermal Insulation and Acoustic Absorption Properties [J].
Suthatho, Anuphong ;
Rattanawongkun, Phattharasaya ;
Tawichai, Nattaya ;
Tanpichai, Supachok ;
Boonmahitthisud, Anyaporn ;
Soykeabkaew, Nattakan .
ACS APPLIED POLYMER MATERIALS, 2023, 6 (01) :390-397
[47]   All-Aramid Composites by Partial Fiber Dissolution [J].
Zhang, Jian Min ;
Mousavi, Zeinab ;
Soykeabkaew, Nattakan ;
Smith, Paul ;
Nishino, Takashi ;
Peijs, Ton .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (03) :919-926
[48]   Preparation of all-cellulose composites with optical transparency using the banana pseudostem as a raw material [J].
Chavez-Guerrero, L. ;
Vazquez-Rodriguez, S. ;
Salinas-Montelongo, J. A. ;
Roman-Quirino, L. E. ;
Garcia-Gomez, N. A. .
CELLULOSE, 2019, 26 (06) :3777-3786
[49]   Rapid preparation of all-cellulose composites by solvent welding based on the use of aqueous solvent [J].
Sirvio, J. A. ;
Visanko, M. ;
Hildebrandt, N. C. .
EUROPEAN POLYMER JOURNAL, 2017, 97 :292-298
[50]   Effect of Processing Conditions on Fracture Resistance and Cohesive Laws of Binderfree All-Cellulose Composites [J].
S. Goutianos ;
R. Arévalo ;
B. F. Sørensen ;
T. Peijs .
Applied Composite Materials, 2014, 21 :805-825