Crystallization characteristics of Ni-W-P composite coatings reinforced by CeO2 and SiO2 nano-particles

被引：3

作者：

Xu Rui-dong ^{[1
,2
]}

Zhai Da-cheng ^{[1
,2
]}

Zhang Yu-zhi ^{[3
]}

机构：

[1] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Peoples R China

[2] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Peoples R China

[3] Chinese Acad Sci, Key Lab Inorgan Coating Mat, Shanghai 200050, Peoples R China

来源：

JOURNAL OF CENTRAL SOUTH UNIVERSITY | 2014年 / 21卷 / 12期

基金：

中国国家自然科学基金;

关键词：

composite coating; double pulse electrodeposition; Ni-W-P; nano-particles; crystallization characteristics; PHASE-TRANSFORMATION BEHAVIOR; MICROSTRUCTURE; PHOSPHORUS; DEPOSITION; MECHANISM; KINETICS; ALLOYS;

D O I：

10.1007/s11771-014-2444-z

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Ni-W-P composite coatings reinforced by CeO2 and SiO2 nano-particles on the surface of common carbon steels, were prepared by double pulse electrodeposition. The crystallization course was characterized by phase structures, crystallinity, grain sizes and microstructures. The results indicate that as-deposited composite coating is amorphous. Whereas it turns into the crystalline structure with 98.25% crystallinity, and Ni3P, Ni2P and Ni5P2 alloy phases precipitate from structures at 400 degrees C. Thereafter, Ni2P and Ni5P2 metastable alloy phases turn into Ni3P stable alloy phase at 500 degrees C. The crystallization course of the composite coating has finished when being heat-treated at 700 degrees C. The average sizes of Ni grains increase with the rise of heat treatment temperature from 400 degrees C to 700 degrees C. CeO2 and SiO2 nano-particles deposited into Ni-W-P alloys can delay the crystallization course and habit the growth of alloy phases.

引用

页码：4424 / 4431

页数：8

共 29 条

[1] Ni-based metal matrix composite functionally graded coatings
Amado, J. M.
Montero, J.
Tobar, M. J.
Yanez, A.
[J]. LASER ASSISTED NET SHAPE ENGINEERING 7 (LANE 2012), 2012, 39 : 362 - 367
[2] Corrosion resistance enhancement of electroless Ni-P coating by incorporation of ultrasonically dispersed diamond nanoparticles
Ashassi-Sorkhabi, Habib
Es'haghi, Moosa
[J]. CORROSION SCIENCE, 2013, 77 : 185 - 193
[3] Electrochemical studies on electroless ternary and quaternary Ni-P based alloys
Balaraju, J. N.
Selvi, V. Ezhil
Grips, V. K. William
Rajam, K. S.
[J]. ELECTROCHIMICA ACTA, 2006, 52 (03) : 1064 - 1074
[4] Phase transformation behavior of nanocrystalline Ni-W-P alloys containing various W and P contents
Balaraju, J. N.
Kalavati
Manikandanath, N. T.
Grips, V. K. William
[J]. SURFACE & COATINGS TECHNOLOGY, 2012, 206 (10) : 2682 - 2689
[5] Electroless deposition of Ni-Cu-P, Ni-W-P and Ni-W-Cu-P alloys
Balaraju, JN
Rajam, KS
[J]. SURFACE & COATINGS TECHNOLOGY, 2005, 195 (2-3) : 154 - 161
[6] Simulation of electrochemical nucleation in the presence of additives under galvanostatic and pulsed plating conditions
Emekli, Ugur
West, Alan C.
[J]. ELECTROCHIMICA ACTA, 2010, 56 (02) : 977 - 984
[7] The study of corrosion-wear mechanism of Ni-W-P alloy
He, F. J.
Fang, Y. Z.
Jin, S. J.
[J]. WEAR, 2014, 311 (1-2) : 14 - 20
[8] Hong B, 2006, ACTA METALL SIN, V42, P699
[9] Structure characterization of nanocrystalline Ni-W alloys obtained by electrodeposition
Indyka, P.
Beltowska-Lehman, E.
Tarkowski, L.
Bigos, A.
Garcia-Lecina, E.
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 590 : 75 - 79
[10] Microstructure and corrosion behavior of electroless deposited Ni-P/CeO2 coating
Jin, Hui Ming
Jiang, Shi Hang
Zhang, Lin Nan
[J]. CHINESE CHEMICAL LETTERS, 2008, 19 (11) : 1367 - 1370

← 1 2 3 →