Nanoscale Mapping of Semi-Crystalline Polypropylene

被引:6
作者
Abrams, Kerry J. [1 ]
Wan, Quan [1 ]
Stehling, Nicola A. [1 ]
Jiao, C. [2 ]
Talari, Abdullah C. S. [1 ]
Rehman, Ihtesham [1 ]
Rodenburg, Cornelia [1 ]
机构
[1] Univ Sheffield, Dept Mat Sci Engn, Sheffield S10 2TN, S Yorkshire, England
[2] Thermo Fisher Sci, Mat & Struct Anal, Achtseweg Noord 5, NL-5651 GG Eindhoven, Netherlands
来源
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 14 NO 12 | 2017年 / 14卷 / 12期
基金
英国工程与自然科学研究理事会;
关键词
hyperspectral imaging; polypropylene; secondary electron spectroscopy; semi-crystalline polymers; ISOTACTIC POLYPROPYLENE; FILMS; CRYSTALLINITY;
D O I
10.1002/pssc.201700153
中图分类号
O59 [应用物理学];
学科分类号
摘要
We reveal nanoscale information of semi-crystalline polypropylene with the use of a new secondary electron hyperspectral imaging technique. The innovative combination of cryo-SEM and low voltage allows for the optimized imaging of these beam-sensitive materials. Through the collection of secondary electron hyperspectral imaging data, mapping of molecular order on the nano-scale in the scanning electron microscope (SEM) can be achieved.
引用
收藏
页数:4
相关论文
共 22 条
[1]   Mesophases in polyethylene, polypropylene, and poly(1-butene) [J].
Androsch, Rene ;
Di Lorenzo, Maria Laura ;
Schick, Christoph ;
Wunderlich, Bernhard .
POLYMER, 2010, 51 (21) :4639-4662
[2]   Quantum dot-polymer composites based on nanoporous polypropylene films with different draw ratios [J].
Bobrovsky, Alexey ;
Shibaev, Valery ;
Abramchuk, Sergey ;
Elyashevitch, Galina ;
Samokhvalov, Pavel ;
Oleinikov, Vladimir ;
Mochalov, Konstantin .
EUROPEAN POLYMER JOURNAL, 2016, 82 :93-101
[3]   The study of room-temperature stretching of annealed polypropylene cast film with row-nucleated crystalline structure [J].
Chen Xiande ;
Xu Ruijie ;
Xie Jiayi ;
Lin Yuanfei ;
Lei Caihong ;
Li Liangbin .
POLYMER, 2016, 94 :31-42
[4]   The Raman spectra of oriented isotactic polypropylene [J].
deBaez, MA ;
Hendra, PJ ;
Judkins, M .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1995, 51 (12) :2117-2124
[5]  
JOY D, 1985, J MICROSC-OXFORD, V140, P282, DOI 10.1111/j.1365-2818.1985.tb02681.x
[6]   Quantitative secondary electron energy filtering in a scanning electron microscope and its applications [J].
Kazemian, P. ;
Mentink, S. A. M. ;
Rodenburg, C. ;
Humphreys, C. J. .
ULTRAMICROSCOPY, 2007, 107 (2-3) :140-150
[7]   Nanoscale Mapping of Bromide Segregation on the Cross Sections of Complex Hybrid Perovskite Photovoltaic Films Using Secondary Electron Hyperspectral Imaging in a Scanning Electron Microscope [J].
Kumar, Vikas ;
Schmidt, Whitney L. ;
Schileo, Giorgio ;
Masters, Robert C. ;
Wong-Stringer, Michael ;
Sinclair, Derek C. ;
Reaney, Ian M. ;
Lidzey, David ;
Rodenburg, Cornelia .
ACS OMEGA, 2017, 2 (05) :2126-2133
[8]   A semi-quantitative deformation model for pore formation in isotactic polypropylene microporous membrane [J].
Lin, Yuanfei ;
Meng, Lingpu ;
Wu, Lihui ;
Li, Xueyu ;
Chen, Xiaowei ;
Zhang, Qianlei ;
Zhang, Rui ;
Zhang, Wenhua ;
Li, Liangbin .
POLYMER, 2015, 80 :214-227
[9]  
LOTZ B, 1991, POLYM BULL, V25, P101
[10]   Sub-nanometre resolution imaging of polymer-fullerene photovoltaic blends using energy-filtered scanning electron microscopy [J].
Masters, Robert C. ;
Pearson, Andrew J. ;
Glen, Tom S. ;
Sasam, Fabian-Cyril ;
Li, Letian ;
Dapor, Maurizio ;
Donald, Athene M. ;
Lidzey, David G. ;
Rodenburg, Cornelia .
NATURE COMMUNICATIONS, 2015, 6