Zeolites for fine chemicals production

被引：128

作者：

Clerici, MG ^{[1
]}

机构：

[1] EniTechnol, I-20097 San Donato Milanese, Italy

来源：

TOPICS IN CATALYSIS | 2000年 / 13卷 / 04期

关键词：

environmental; fine chemicals; zeolite; acid catalysts; redox catalysis; Ti-zeolite;

D O I：

10.1023/A:1009063106954

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The use of zeolitic catalysts in organic syntheses is reviewed with emphasis on recent developments in the areas of acid and redox catalysis and on their relationship with environmental issues. Examples of acid-catalyzed reactions are chosen from the acylation, alkylation, hydroxyalkylation of aromatic and heterocyclic compounds and from rearrangement reactions. The epoxidation of olefins, the hydroxylation of arenes and the oxidation of O-, S- and N-functionalities with hydrogen peroxide on Ti-zeolites illustrate catalyzed oxidations.

引用

页码：373 / 386

页数：14

共 114 条

[1] Diastereoselective epoxidation of allylic alcohols with hydrogen peroxide catalyzed by titanium-containing zeolites or methyltrioxorhenium versus stoichiometric oxidation with dimethyldioxirane: Clues on the active species in the zeolite lattice [J].