Online estimation of lithium-ion battery remaining discharge capacity through differential voltage analysis

The estimation of battery remaining discharge capacity (Q(RDC)) is essential for the remaining driving range prediction on pure electric vehicles. A traditional Q(RDC) estimation method is based on the determination of battery state of charge (SOC), in which the estimation accuracy could be affected by the variation in discharge conditions. In this research, a novel Q(RDC) estimation method through differential voltage (dV/dQ) analysis is introduced for lithium-ion batteries. Through analyzing the characteristics of terminal voltage variation, the present Q(RDC) could be estimated by the dV/dQ value, which is capable to provide an accurate estimation result under various discharge conditions. On a commercial lithium-ion battery, the dV/dQ method is implemented for Q(RDC) estimation under pulse discharge profiles and dynamic profiles. The result shows that the dV/dQ method could provide accurate Q(RDC) estimation results under various discharge profiles in the latter part of the discharge process, and the Q(RDC) estimation accuracy could hence be improved by combining the differential voltage analysis with the SOC-based method. Owing to the simple computation process, the dV/dQ-based estimation method is very competitive in onboard applications. (C) 2014 Elsevier B.V. All rights reserved.