Stable-jet length controlling electrospun fiber radius: Model and experiment

被引:15
作者
Lei, Sailing [1 ]
Quan, Zhenzhen [1 ,2 ]
Zhang, Hongnan [1 ]
Qin, Xiaohong [1 ]
Wang, Rongwu [1 ]
Yu, Jianyong [2 ]
机构
[1] Donghua Univ, Coll Text, Key Lab Text Sci & Technol, Minist Educ, Shanghai 201620, Peoples R China
[2] Donghua Univ, Innovat Ctr Text Sci & Technol, Shanghai 201620, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Electrospinning; Stable-jet length; Terminal fiber radius; ELECTRICALLY FORCED JETS; SCALING LAWS; POLYMER-SOLUTIONS; INSTABILITY; DIAMETER; DYNAMICS; CONE; SIZE;
D O I
10.1016/j.polymer.2019.121762
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Generally, the precise prediction and control on the radius of electrospun polymer fibers is critical for their applications but still remains challenging. In the current work, a model has been established to predict the radius. It is shown that the correlation between the stable-jet length and the terminal fiber radius satisfies a scaling law with a power exponent -2/3 for fully charged fibers, while the exponent becomes smaller for the case in which the fibers are partly charged on surface during electrospinning. And a good agreement between the experimental and theoretical values for electrospinning poly(methyl methacrylate) (PMMA) fibers is obtained, thus further verifying the correctness of derived model between the stable-jet length and the terminal fiber radius.
引用
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页数:7
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