Review on chemically bonded geminis with cationic heads: second-generation interfactants

被引：43

作者：

Mondal, Monohar Hossain ^{[1
]}

Roy, Ankit ^{[1
]}

Malik, Susanta ^{[1
]}

Ghosh, Aniruddha ^{[1
]}

Saha, Bidyut ^{[1
]}

机构：

[1] Univ Burdwan, Dept Chem, Homogeneous Catalysis Lab, Burdwan 713104, W Bengal, India

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2016年 / 42卷 / 03期

关键词：

Cationic gemini; Dimeric surfactants; Green chemistry; Catalysis; TO-MICELLE TRANSITION; CHAIN-LENGTH; ANTIMICROBIAL ACTIVITY; DIMERIC SURFACTANTS; ORGANIC-CHEMISTRY; BINARY-MIXTURE; SPACER GROUP; BEHAVIOR; AMPHIPHILES; TENSION;

D O I：

10.1007/s11164-015-2125-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic gemini surfactants are a special class of second-generation smart surfactants. Since Menger first named them, gemini surfactants have drawn a wide and immense attraction from scientists throughout the whole world. These dimeric surfactants possess two or more hydrophilic with two or more hydrophobic head groups, chemically bonded with a linker, called the spacer group. These kinds of surfactants are used mainly in homogeneous catalytic reactions, as well as for solubilisation, emulsification, and many more technical applications. They are used in industries for electro-decoating, stabilization of adhesive polymer latex, anti-friction agents, mining, paper manufacturing, preparation of surfactants including softeners, cosmetics, and most importantly, recent advancement in drug designing, synthesis, and application in medicine. The aim of this paper is to bring attention to the high performance second generation interfactants, with a focus on their synthesis, structure, types, and greener industrial application with high possibility of future prospect.

引用

页码：1913 / 1928

页数：16