Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling

被引：55

作者：

Ahmad, Muhammad Sajjad ^{[1
,5
]}

Klemes, Jiri Jaromir ^{[2
]}

Alhumade, Hesham ^{[3
,4
]}

Elkamel, Ali ^{[5
]}

Mahmood, Abid ^{[6
]}

Shen, Boxiong ^{[1
]}

Ibrahim, Muhammad ^{[6
]}

Mukhtar, Ahmad ^{[7
]}

Saqib, Sidra ^{[8
]}

Asif, Saira ^{[2
,9
]}

Bokhari, Awais ^{[2
,8
]}

机构：

[1] Hebei Univ Technol, Sch Energy & Environm Engn, Tianjin Key Lab Clean Energy & Pollut Control, Tianjin 300401, Peoples R China

[2] Brno Univ Technol, Fac Mech Engn, NETME Ctr, Sustainable Proc Integrat Lab,SPIL,VUT Brno, Tech 2896-2, Brno 61669, Czech Republic

[3] King Abdulaziz Univ, Fac Engn, Dept Chem & Mat Engn, Jeddah 21589, Saudi Arabia

[4] King Abdulaziz Univ, Ctr Res Excellence Renewable Energy & Power Syst, Jeddah 21589, Saudi Arabia

[5] Univ Waterloo, Dept Chem Engn, 200 Ave West, Waterloo, ON N2L 3G1, Canada

[6] Govt Coll Univ Faisalabad, Dept Environm Sci & Engn, Faisalabad 38000, Pakistan

[7] Univ Teknol PETRONAS, Dept Chem Engn, Seri Iskandar 32610, Perak, Malaysia

[8] COMSATS Univ Islamabad CUI, Dept Chem Engn, Lahore Campus, Lahore 54000, Punjab, Pakistan

[9] PMAS Arid Agr Univ, Fac Sci, Dept Bot, Rawalpindi 46300, Punjab, Pakistan

来源：

FUEL | 2021年 / 293卷

关键词：

Biomass; Pyrolysis; TGA; Kinetic parameters; Bioenergy; THERMOGRAVIMETRIC ANALYSIS; DECOMPOSITION KINETICS; THERMOCHEMICAL CONVERSION; THERMODYNAMICS PARAMETERS; HEATING RATE; BIOMASS; GRASS; COMBUSTION; PRODUCTS; ENERGY;

D O I：

10.1016/j.fuel.2021.120349

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The present study aims to evaluate the feasibility of Maple Leaf Waste (MLW) for the first time to produce biofuel-bioenergy and chemicals. It is meaningful to understand the thermochemical conversion and degradation pattern of the MLW to evaluate its biofuel-bioenergy potential. Different degradation stages and zones based on temperature and mass loss were identified to understand the pyrolytic behaviour in depth. Four different heating rates were used to conduct kinetic and thermodynamic analysis. The pyrolysis temperature was concluded ranged from 200 degrees C to 430 degrees C at all heating rates to obtain maximum bioenergy products. The kinetic parameters of pyrolysis were obtained by analysing through iso-conversional models of Kissinger-Akahira-Sunose (KAS), Friedman and Flynn-Wall-Ozawa (FWO). The average values of activation energies (75-91 kJ mol(-1)), high heating values (16.32 MJ kg(-1)), Gibb's free energies (261-269 kJ mol(-1)) and change in enthalpy (68-85 kJ mol(-1)) have shown the significant potential for bioenergy production and suitability of co-pyrolysis with other waste and biomass feedstock.

引用

页数：8

共 63 条

[1] CO-PYROLYSIS OF OLIVE RESIDUE WITH POLY(VINYL CHLORIDE) USING THERMOGRAVIMETRIC ANALYSIS [J].