Dichlorodimethylsilane mediated one-step synthesis of hydrophilic and hydrophobic silica nanoparticles

被引:33
作者
Ebrahimi, F. [1 ]
Farazi, R. [2 ]
Karimi, E. Z. [3 ]
Beygi, H. [1 ]
机构
[1] Ferdowsi Univ Mashhad, Fac Engn, Dept Mat Sci & Met Engn, Mashhad, Iran
[2] Mat & Energy Res Ctr, Nanotechnol & Adv Mat Dept, Karaj, Iran
[3] Islamic Azad Univ, Mashhad Branch, Dept Met & Ceram, Mashhad, Iran
关键词
One-step synthesis; Silica nanoparticles; Hydrophilic and hydrophobic; Transmission electron microscopy (TEM); SURFACE;
D O I
10.1016/j.apt.2016.12.022
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Hydrophilic and hydrophobic silica nanoparticles were synthesized by a cheap, simple and low temperature one-step method. The method involves a catalytic reaction between ammonium hydroxide, tetraethyl orthosilicate (TEOS) and dichlorodimethylsilane (DDS) in an ethanol solvent. The effects of different parameters such as chemical concentration and reaction temperature were investigated on size of the synthesized silica particles. Characterizations of hydrophilic and hydrophobic particles were performed using dynamic light scattering (DLS), X-ray diffraction analysis (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). According to the results, by reducing the amount of ammonium hydroxide, ethanol and temperature, the size of hydrophilic silica particles can be reduced to 129 +/- 10.4 nm. Other sides, addition of DDS agent caused to silica particles found hydrophobic property and size of the particles reduced to about 65 +/- 6.5 nm. (C) 2016 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
引用
收藏
页码:932 / 937
页数:6
相关论文
共 19 条
[1]   Synthesis of Silica Nanoparticles by Sol-Gel: Size-Dependent Properties, Surface Modification, and Applications in Silica-Polymer Nanocomposites-A Review [J].
Ab Rahman, Ismail ;
Padavettan, Vejayakumaran .
JOURNAL OF NANOMATERIALS, 2012, 2012
[2]   The fracture and fatigue behaviour of nano-modified epoxy polymers [J].
Blackman, B. R. K. ;
Kinloch, A. J. ;
Lee, J. Sohn ;
Taylor, A. C. ;
Agarwal, R. ;
Schueneman, G. ;
Sprenger, S. .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (16) :7049-7051
[3]   One-pot synthesis of sub-50 nm vinyl- and acrylate-modified silica nanoparticles [J].
Effati, Elham ;
Pourabbas, Behzad .
POWDER TECHNOLOGY, 2012, 219 :276-283
[4]   SYNTHESIS OF MONODISPERSED SILICA POWDERS .2. CONTROLLED GROWTH REACTION AND CONTINUOUS PRODUCTION PROCESS [J].
GIESCHE, H .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1994, 14 (03) :205-214
[5]   A method for dispersing dry nano-sized particles in a liquid using carrier particles [J].
Gotoh, Kuniaki ;
Kawazu, Takashi ;
Yoshida, Mikio ;
Oshitani, Jun .
ADVANCED POWDER TECHNOLOGY, 2010, 21 (01) :34-40
[6]   Development of preparation method to control silica sol-gel synthesis with rheological and morphological measurements [J].
Kaide, Aya ;
Saeki, Takashi .
ADVANCED POWDER TECHNOLOGY, 2014, 25 (02) :773-779
[7]   Functionally modified monodisperse core-shell silica nanoparticles: Silane coupling agent as capping and size tuning agent [J].
Lin, Jinbin ;
Chen, Hongling ;
Ji, Yan ;
Zhang, Yu .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 411 :111-121
[8]   Functionally modified core-shell silica nanoparticles by one-pot synthesis [J].
Marini, Michele ;
Pourabbas, Behzad ;
Pilati, Francesco ;
Fabbri, Paola .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 317 (1-3) :473-481
[9]   Effect of surface modification of silica particles on interaction forces and dispersibility in suspension [J].
Mori, Takeshi ;
Okada, Yohei ;
Kamiya, Hidehiro .
ADVANCED POWDER TECHNOLOGY, 2016, 27 (03) :830-838
[10]  
Niederberger M, 2009, ENG MATER PROCESS, P1, DOI 10.1007/978-1-84882-671-7