Star-epoxy mesogen with 1,3,5-triazine core: a model of A4B3 fractal polymerization in a liquid crystalline thermoset media

被引：14
作者：
Pin, Jean-Mathieu [1 ]
Sbirrazzuoli, Nicolas
Sacarescu, Liviu [2 ]
Mija, Alice [1 ]
机构：
[1] Univ Nice Sophia Antipolis, LPMC, CNRS, UMR 7336, Parc Valrose, F-06108 Nice 2, France
[2] Inst Chim Macromol Petru Poni Aleea Grigore Ghica, 41A, Iasi 700487, Romania
来源：
POLYMER CHEMISTRY | 2016年 / 7卷 / 06期
关键词：
ANTIBACTERIAL ACTIVITY; MECHANICAL-PROPERTIES; THERMAL-DEGRADATION; RIGID-ROD; KINETICS; RESINS; DENDRIMERS; SCATTERING; TOPOLOGY; POLYMERS;
D O I：
10.1039/c5py01884f
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A star-epoxy monomer (TriaEP) has been synthesized by the creation of a 1,3,5-triazine core. Its association with an aromatic di-amine reveals an A(4)B(3) cross-linked polymer that exhibits a complex mechanism of self-assembly. These architectural aspects, resulting from both fractal polymerization and mesophase growth, are discussed in regard to its outstanding thermo-mechanical properties.
引用
收藏
页码：1221 / 1225
页数：5
相关论文
共 56 条
  • [1] GELLED NETWORKS PREPARED FROM RIGID FRACTAL POLYMERS
    AHARONI, SM
    [J]. MACROMOLECULES, 1991, 24 (01) : 235 - 239
  • [2] FRACTAL NATURE OF ONE-STEP HIGHLY BRANCHED RIGID RODLIKE MACROMOLECULES AND THEIR GELLED-NETWORK PROGENIES
    AHARONI, SM
    MURTHY, NS
    ZERO, K
    EDWARDS, SF
    [J]. MACROMOLECULES, 1990, 23 (09) : 2533 - 2549
  • [3] AHARONI SM, 1994, ADV POLYM SCI, V118
  • [4] Functional Supramolecular Polymers
    Aida, T.
    Meijer, E. W.
    Stupp, S. I.
    [J]. SCIENCE, 2012, 335 (6070) : 813 - 817
  • [5] Physical and mechanical properties of flexible polybenzoxazine resins: Effect of aliphatic diamine chain length
    Allen, Douglas J.
    Ishida, Hatsuo
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (05) : 2798 - 2809
  • [6] [Anonymous], 2011, HDB LIQUID CRYSTALS
  • [7] HIERARCHICAL STRUCTURE IN POLYMERIC MATERIALS
    BAER, E
    HILTNER, A
    KEITH, HD
    [J]. SCIENCE, 1987, 235 (4792) : 1015 - 1022
  • [8] LIQUID-CRYSTALLINE AND RIGID-ROD NETWORKS
    BARCLAY, GG
    OBER, CK
    [J]. PROGRESS IN POLYMER SCIENCE, 1993, 18 (05) : 899 - 945
  • [9] OXIDATIVE SKELETON BREAKING IN EPOXY-AMINE NETWORKS
    BELLENGER, V
    VERDU, J
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (01) : 363 - 374
  • [10] THERMOGRAVIMETRIC STUDY OF AMINE CROSS-LINKED EPOXIES
    BELLENGER, V
    FONTAINE, E
    FLEISHMANN, A
    SAPORITO, J
    VERDU, J
    [J]. POLYMER DEGRADATION AND STABILITY, 1984, 9 (04) : 195 - 208
123456