Aqueous 1,3-dipolar cycloadditions promoted by copper nanoparticles in polydiacetylene micelles

被引：41

作者：

Clarisse, Damien ^{[1
]}

Prakash, Praveen ^{[1
]}

Geertsen, Valerie ^{[2
]}

Miserque, Frederic ^{[3
]}

Gravel, Edmond ^{[1
]}

Doris, Eric ^{[1
]}

机构：

[1] Univ Paris Saclay, SCBM, CEA, F-91191 Gif Sur Yvette, France

[2] Univ Paris Saclay, CNRS, NIMBE, CEA, F-91191 Gif Sur Yvette, France

[3] Univ Paris Saclay, Serv Etud Corros & Comportement Mat Environm SCCM, CEA, F-91191 Gif Sur Yvette, France

来源：

GREEN CHEMISTRY | 2017年 / 19卷 / 13期

关键词：

AZIDE-ALKYNE CYCLOADDITION; CLICK CHEMISTRY; TERMINAL ALKYNES; HETEROGENEOUS CATALYSIS; DRUG-DELIVERY; NANOCRYSTALS; WATER;

D O I：

10.1039/c7gc01017f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel colloidal catalyst was developed through the encapsulation of cuprous oxide nanoparticles in polydiacetylene micelles. The Cu-based catalyst was applied to the Huisgen cycloaddition reaction in fully aqueous medium. The process neither requires heating nor a controlled atmosphere and the catalyst can be recycled in subsequent reactions without any loss of activity.

引用

页码：3112 / 3115

页数：4

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