Application of triacylglycerol and fatty acid analyses to discriminate blended sesame oil with soybean oil

被引:67
作者
Park, Young Woo [1 ]
Chang, Pahn-Shick [2 ]
Lee, JaeHwan [1 ]
机构
[1] Seoul Natl Univ Technol, Dept Food Sci & Technol, Seoul 139743, South Korea
[2] Seoul Natl Univ, Dept Agr Biotechnol, Seoul 151921, South Korea
关键词
Blended sesame oil; Triacylglycerols; Fatty acids; HPLC-ELSD; GC-FID; REFINED OLIVE OIL; HAZELNUT OIL; LIQUID-CHROMATOGRAPHY; ADULTERATION;
D O I
10.1016/j.foodchem.2010.04.049
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Triacylglycerols (TAGS) and fatty acids in the mixture of sesame oil (SO) with soybean oil were analysed using high performance liquid chromatography (HPLC)-an evaporative light scattering detector (ELSD) and gas chromatography (GC)-a flame ionisation detector (FID). Relative percentage of linolenic acid increased rapidly compared to those of oleic and linoleic acids as the ratio of soybean oil increased in the blended SO. Peak responses of trilinolein (LLL) and trilinolenin (LnLnLn) by HPLC-ELSD was higher than those by GC-FID from the same concentration of TAGs. The presence of LLLn peak, the contents of linolenic acid, and the relative ratio of L/S, O/Ln, and L/Ln from fatty acids or LLL/OOO from TAGs could be useful indicators to detect the blended SO with soybean oil. TAG analysis by HPLC-ELSD coupled with fatty acids by GC-FID can be useful methods to discriminate blended SO with soybean oil. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:377 / 383
页数:7
相关论文
共 26 条
[11]  
강치희, 2002, [Journal of the Korean Society of Food Science and Nutrition, 한국식품영양과학회지], V31, P17
[12]   Reversed phase liquid chromatographic determination of triacylglycerol composition in sesame oils and the chemometric detection of adulteration [J].
Lee, DS ;
Lee, ES ;
Kim, HJ ;
Kim, SO ;
Kim, K .
ANALYTICA CHIMICA ACTA, 2001, 429 (02) :321-330
[13]  
Lee J, 2007, FOOD SCI BIOTECHNOL, V16, P981
[14]   Effects of roasting conditions of sesame seeds on the oxidative stability of pressed oil during thermal oxidation [J].
Lee, Seung Wook ;
Jeung, Min Kyu ;
Park, Min Hee ;
Lee, Soo Yong ;
Lee, JaeHwan .
FOOD CHEMISTRY, 2010, 118 (03) :681-685
[15]   ANTIOXIDANTS ANTIMUTAGENS IN FOOD [J].
NAMIKI, M .
CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION, 1990, 29 (04) :273-300
[16]   Detection of hazelnut oil adulteration using FT-IR spectroscopy [J].
Ozen, BF ;
Mauer, LJ .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (14) :3898-3901
[17]   Determination of rat liver triglycerides by gas-liquid chromatography and reversed-phase high-performance liquid chromatography [J].
Perona, JS ;
Barrón, LJR ;
Ruiz-Gutiérrez, V .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 1998, 706 (02) :173-179
[18]   Detection of the presence of refined hazelnut oil in refined olive oil by fluorescence spectroscopy [J].
Sayago, A. ;
Garcia-Gonzalez, D. L. ;
Morales, M. T. ;
Aparicio, R. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (06) :2068-2071
[19]  
Shahidi F., 2004, PHENOLICS FOOD NUTRA, P108
[20]  
Shin Jung-Ah, 2005, [Korean Journal of Food Science and Technology, 한국식품과학회지], V37, P856