Gamma radiation effect on sisal / polyurethane composites without coupling agents

被引:15
作者
Vasco, Marina Cardoso [1 ]
Neto, Salvador Claro [2 ]
Nascimento, Eduardo Mauro [3 ]
Azevedo, Elaine [3 ]
机构
[1] Univ Patras, Dept Mech Engn & Aerosp, Patras, Greece
[2] Univ Sao Paulo, Inst Qum Sao Carlos, Sao Carlos, SP, Brazil
[3] Univ Tecnol Fed Parana UTFPR, Programa Posgrad Engn Mecan & Mat, Curitiba, Parana, Brazil
来源
POLIMEROS-CIENCIA E TECNOLOGIA | 2017年 / 27卷 / 02期
关键词
gamma radiation; sisal; polyurethane; mechanical properties; green composite; NATURAL CELLULOSE FIBERS; VEGETABLE FIBERS; SURFACE MODIFICATION; CHEMICAL TREATMENT; BIOCOMPOSITES; KINETICS; DEGRADATION; IMPROVEMENT; INTERFACE; BEHAVIOR;
D O I
10.1590/0104-1428.05916
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Natural fibers and polyurethane based composites may present chemical bonding between the components of the polymer and the lignin of the fiber. The incidence of radiation can cause degradation of the polymeric material and alter its mechanical properties. The objective of this study was to obtain and characterize cold pressed composites from polyurethane derived from castor oil and sisal fibers, without coupling agents, through thermogravimetric and mechanical tests, before and after the incidence of 25 kGy dose of gamma radiation. Woven composites that were not irradiated had maximum values of 4.40 GPa for flexural elastic modulus on three point flexural test and dispersed fiber composite that were not irradiated had maximum values of 2.25 GPa. These materials are adequate for use in non-structural applications in radiotherapy and radiodiagnostic rooms.
引用
收藏
页码:165 / 170
页数:6
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