Visible-Light-Induced Photocatalytic Synthesis of β-Keto Dithiocarbamates via Difunctionalization of Styrenes

被引：56
|
作者：
Vishwakarma, Ramesh Kumar [1 ]
Kumar, Saurabh [1 ]
Singh, Krishna Nand [1 ]
机构：
[1] Banaras Hindu Univ, Inst Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
ORGANIC LETTERS | 2021年 / 23卷 / 11期
关键词：
FACILE SYNTHESIS; DNA-BINDING; DERIVATIVES; INHIBITION; MECHANISM; ALKENES;
D O I：
10.1021/acs.orglett.1c01059
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A facile photocatalyzed strategy for difunctionalization of styrenes in the presence of CS2 and amines providing beta-keto dithiocarbamates has been developed. In the case of 4-nitrostyrene and 2-vinylpyridine, however, only 2-arylethylthiocarbamates are interestingly formed without the aid of photoredox catalysis/TBHP.
引用
收藏
页码：4147 / 4151
页数：5
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