Discrimination and Characterization of the Volatile Organic Compounds in Schizonepetae Spica from Six Regions of China Using HS-GC-IMS and HS-SPME-GC-MS

被引：21

作者：

Li, Chao ^{[1
]}

Wan, Huiying ^{[1
]}

Wu, Xinlong ^{[1
]}

Yin, Jiaxin ^{[1
]}

Zhu, Limin ^{[2
]}

Chen, Hanjiang ^{[2
]}

Song, Xinbo ^{[1
,3
,4
]}

Han, Lifeng ^{[3
,4
]}

Yang, Wenzhi ^{[3
,4
]}

Yu, Heshui ^{[1
,2
,3
]}

Li, Zheng ^{[1
,2
,3
]}

机构：

[1] Tianjin Univ Tradit Chinese Med, Coll Pharmaceut Engn Tradit Chinese Med, Tianjin 301617, Peoples R China

[2] Tianjin Univ Tradit Chinese Med, Teaching Hosp 1, Tianjin 300193, Peoples R China

[3] Tianjin Univ Tradit Chinese Med, Haihe Lab Modern Chinese Med, Tianjin 301617, Peoples R China

[4] Tianjin Univ Tradit Chinese Med, State Key Lab Component Based Chinese Med, Tianjin 301617, Peoples R China

来源：

MOLECULES | 2022年 / 27卷 / 14期

基金：

中国国家自然科学基金;

关键词：

volatile organic compounds; Schizonepetae Spica; HS-SPME-GC-MS; HS-GC-IMS; OPLS-DA; TENUIFOLIA;

D O I：

10.3390/molecules27144393

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Volatile organic compounds (VOCs) are the main chemical components of Schizonepetae Spica (SS), which have positive effects on the quality evaluation of SS. In this study, HS-SPME-GC-MS (headspace solid-phase microextraction-gas chromatography-mass spectrometry) and HS-GC-IMS (headspace-gas chromatography-ion mobility spectrometry) were performed to characterize the VOCs of SS from six different regions. A total of 82 VOCs were identified. In addition, this work compared the suitability of two instruments to distinguish SS from different habitats. The regional classification using orthogonal partial least squares discriminant analysis (OPLS-DA) shows that the HS-GC-IMS method can classify samples better than the HS-SPME-GC-MS. This study provided a reference method for identification of the SS from different origins.

引用

页数：16

共 42 条

[1] Untargeted headspace gas chromatography - Ion mobility spectrometry analysis for detection of adulterated honey [J].

Arroyo-Manzanares, Natalia ;

Garcia-Nicolas, Maria ;

Castell, Ana ;

Campillo, Natalia ;

Vinas, Pilar ;

Lopez-Garcia, Ignacio ;

Hernandez-Cordoba, Manuel .

TALANTA, 2019, 205

[2] Spectrum-effect relationship between GC-QTOF-MS fingerprint and antioxidant, anti-inflammatory activities of Schizonepeta tenuifolia essential oil [J].

Bai, Xi ;

Liu, Liu ;

Zhang, Junping ;

Chen, Li ;

Wu, Tao ;

Aisa, Haji Akber ;

Maiwulanjiang, Maitinuer .

BIOMEDICAL CHROMATOGRAPHY, 2021, 35 (07)

[3] Qualitative analysis of Schizonepeta annua (Pall.) Schischk essential oil by gas chromatography-quadrupole time-of-flight mass spectrometry [J].

Bai, Xi ;

Maitusong, Jumai ;

Mahinur, Bakri ;

Aisa, Haji A. ;

Maiwulanjiang, Maitinuer .

EUROPEAN JOURNAL OF MASS SPECTROMETRY, 2018, 24 (06) :454-462

[4] Effects of pretreatment methods and leaching methods on jujube wine quality detected by electronic senses and HS-SPME-GC-MS [J].

Cai, Wenchao ;

Tang, Fengxian ;

Guo, Zhuang ;

Guo, Xin ;

Zhang, Qin ;

Zhao, Xinxin ;

Ning, Ming ;

Shan, Chunhui .

FOOD CHEMISTRY, 2020, 330

[5] Non-Targeted Screening Approaches for Profiling of Volatile Organic Compounds Based on Gas Chromatography-Ion Mobility Spectroscopy (GC-IMS) and Machine Learning [J].

Capitain, Charlotte ;

Weller, Philipp .

MOLECULES, 2021, 26 (18)

[6] Aroma analysis by GC/MS and electronic nose dedicated to Negroamaro and Primitivo typical Italian Apulian wines [J].

Capone, Simonetta ;

Tufariello, Maria ;

Francioso, Luca ;

Montagna, Giovanni ;

Casino, Flavio ;

Leone, Alessandro ;

Siciliano, Pietro .

SENSORS AND ACTUATORS B-CHEMICAL, 2013, 179 :259-269

[7]

Chen M.T., 2020, NAT PROD RES DEV, V32, P1087

[8] Discrimination of Chinese Yellow Wine from Different Origins Based on Flavor Fingerprint [J].

Chen, Tong ;

Qi, Xingpu ;

Chen, Mingjie ;

Lu, Daoli ;

Chen, Bin .

ACTA CHROMATOGRAPHICA, 2020, 32 (02) :139-144

[9] Variations of volatile flavour compounds in finger citron (Citrus medico L. var. sarcodactylis) pickling process revealed by E-nose, HS-SPME-GC-MS and HS-GC-IMS [J].

Chen, Xiaoai ;

Chen, Haiqiang ;

Xiao, Jie ;

Liu, Jingyi ;

Tang, Niang ;

Zhou, Aimei .

FOOD RESEARCH INTERNATIONAL, 2020, 138

[10] Adulteration detection of essence in sesame oil based on headspace gas chromatography-ion mobility spectrometry [J].

Dou, Xinjing ;

Zhang, Liangxiao ;

Yang, Ruinan ;

Wang, Xiao ;

Yu, Li ;

Yue, Xiaofeng ;

Ma, Fei ;

Mao, Jin ;

Wang, Xiupin ;

Li, Peiwu .

FOOD CHEMISTRY, 2022, 370

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