Preparation of biomass-activated porous carbons derived from torreya grandis shell for high-performance supercapacitor

被引:36
作者
Xuan, Huaqing [1 ]
Lin, Gaoxin [1 ]
Wang, Fan [1 ]
Liu, Jiyang [1 ]
Dong, Xiaoping [1 ]
Xi, Fengna [1 ]
机构
[1] Zhejiang Sci Tech Univ, Dept Chem, 928 Second Ave, Hangzhou, Zhejiang, Peoples R China
关键词
Biomass-derived activated carbon; Torreya grandis shell; KOH activation; Supercapacitor; High capacitance; DOUBLE-LAYER CAPACITORS; HIGH-SURFACE-AREA; ENERGY-STORAGE; ELECTROCHEMICAL CAPACITANCE; GRAPHENE NANOSHEETS; FORMALDEHYDE RESIN; ELECTRODE MATERIAL; MESOPOROUS CARBON; NANOSTRUCTURES; CARBONIZATION;
D O I
10.1007/s10008-017-3562-y
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this paper, we reported a novel biomass-derived porous carbon from torreya grandis shell for the first time by means of carbonization and KOH activation under N-2. The pore structures were related to the ratio of KOH and activation temperature. N-2 adsorption-desorption tests indicated that the sample of AC-800-3 has a maximum specific surface area of 2100.8 m(2) g(-1) and proper pore volume of 1.02 cm(3) g(-1). The electrode prepared with AC-800-3 realized a high capacitance of 290.5 F g(-1) at 0.5 A g(-1) and excellent rate capability of 62.6% in three-electrode system. The assembled symmetrical cell of AC-800-3 electrode exhibited a high energy density of 13.5 W h kg(-1) at a power density of 360.1 W kg(-1) in the potential range of 0-1.6 V and excellent cycling stability with 93.1% retention of the initial capacitance after 5000 cycles.
引用
收藏
页码:2241 / 2249
页数:9
相关论文
共 61 条
[1]   Skeleton of Euplectella sp.:: Structural hierarchy from the nanoscale to the macroscale [J].
Aizenberg, J ;
Weaver, JC ;
Thanawala, MS ;
Sundar, VC ;
Morse, DE ;
Fratzl, P .
SCIENCE, 2005, 309 (5732) :275-278
[2]   ZnCl2-activated porous carbon spheres with high surface area and superior mesoporous structure as an efficient supercapacitor electrode [J].
Chang, Binbin ;
Wang, Yiliang ;
Pei, Kemei ;
Yang, Shengmao ;
Dong, Xiaoping .
RSC ADVANCES, 2014, 4 (76) :40546-40552
[3]   Surface amorphization and deoxygenation of graphene oxide paper by Ti ion implantation [J].
Chen, Jiangtao ;
Zhang, Guangan ;
Luo, Baomin ;
Sun, Dongfei ;
Yan, Xingbin ;
Xue, Qunji .
CARBON, 2011, 49 (09) :3141-3147
[4]   Development of a Green Supercapacitor Composed Entirely of Environmentally Friendly Materials [J].
Dyatkin, Boris ;
Presser, Volker ;
Heon, Min ;
Lukatskaya, Maria R. ;
Beidaghi, Majid ;
Gogotsi, Yury .
CHEMSUSCHEM, 2013, 6 (12) :2269-2280
[5]   Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors [J].
El-Kady, Maher F. ;
Strong, Veronica ;
Dubin, Sergey ;
Kaner, Richard B. .
SCIENCE, 2012, 335 (6074) :1326-1330
[6]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[7]   Energy storage in electrochemical capacitors: designing functional materials to improve performance [J].
Hall, Peter J. ;
Mirzaeian, Mojtaba ;
Fletcher, S. Isobel ;
Sillars, Fiona B. ;
Rennie, Anthony J. R. ;
Shitta-Bey, Gbolahan O. ;
Wilson, Grant ;
Cruden, Andrew ;
Carter, Rebecca .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (09) :1238-1251
[8]   A study on high electrochemical capacitance of ion exchange resin-based activated carbons for supercapacitor [J].
Han, Sang-Jin ;
Kim, Young-Ha ;
Kim, Ki-Seok ;
Park, Soo-Jin .
CURRENT APPLIED PHYSICS, 2012, 12 (04) :1039-1044
[9]   Application of biomass-derived flexible carbon cloth coated with MnO2 nanosheets in supercapacitors [J].
He, Shuijian ;
Chen, Wei .
JOURNAL OF POWER SOURCES, 2015, 294 :150-158
[10]   Facile preparation of mesoporous carbons for supercapacitors by one-step microwave-assisted ZnCl2 activation [J].
He, Xiaojun ;
Li, Ruchun ;
Han, Jiufeng ;
Yu, Moxin ;
Wu, Mingbo .
MATERIALS LETTERS, 2013, 94 :158-160