The vaporization enthalpies and vapor pressures of a series of unsaturated fatty acid methyl esters by correlation gas chromatography

被引：33

作者：

Lipkind, Dmitry ^{[1
]}

Kapustin, Yaroslav ^{[1
]}

Umnahanant, Patamaporn ^{[1
]}

Chickos, James S. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA

来源：

THERMOCHIMICA ACTA | 2007年 / 456卷 / 02期

关键词：

FAMEs; vapor pressure; vaporization enthalpy; correlation gas chromatography;

D O I：

10.1016/j.tca.2007.02.008

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vaporization enthalpies for methyl myristoleate (methyl Z 9-tetradecenonate), methyl 10-pentadecenoate, methyl palmitoleate (methyl Z 9-hexadecenoate), methyl Z 10-heptadecenoate, methyl oleate (methyl Z 9-octadecenoate), methyl linoleate (methyl Z,Z 9,12-octadecadienoate), methyl linolenate (methyl Z,Z,Z 9,12,15-octadecatrienoate), methyl Z 11-eicosenoate, methyl Z,Z 11, 14-eicosadienoate, methyl Z,Z,Z 11, 14,17-eicosatrieneoate, methyl arachidonate (methyl Z,Z,Z,Z 5,8,11,14-eicosatetraeneoate), methyl Z,Z,Z,Z,Z 5,8,11,14,17-eicosapentaeneoate, methyl erucate (methyl Z 13-docosaneoate), methyl Z,Z 13,16-docosadienoate, methyl Z,Z,Z,Z,Z,Z 4,7,10,13,16,19-docosahexaenoate and methyl nervonate (methyl Z 15-tetracosenoate) are evaluated at T=298.15 and vapor pressures are evaluated over the temperature range T=298.15-450 K by correlation gas chromatography. The results are generated by an interpolative process using literature values for the saturated fatty acid methyl esters (FAMEs) from methyl decanoate to methyl tetracosanoate, exclusive of methyl nonadecanoate, heneicosanoate and tricosanoate, as standards. Relationships for calculating vapor pressures for all of the compounds studied from T=298.15 to 450 K are provided. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：94 / 101

页数：8

共 38 条

[21] Vapor pressures and enthalpies of vaporization of a series of 1-and 2-halogenated naphthalenes [J].

Verevkin, SP .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2003, 35 (08) :1237-1251

[22] Determination of vapor pressures, enthalpies of sublimation, enthalpies of vaporization, and enthalpies of fusion of a series of chloro-aminobenzenes and chloro-nitrobenzenes [J].

Verevkin, SP ;

Schick, C .

FLUID PHASE EQUILIBRIA, 2003, 211 (02) :161-177

[23] The vaporization enthalpy and vapor pressure of S (+)-methamphetamine at T=298.15 K by correlation gas chromatography [J].

Thornton, Melissa ;

Gobble, Chase ;

Chickos, James .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2014, 73 :51-56

[24] Prediction of vapor pressure of fatty acid methyl esters [J].

Saxena, Parag ;

Patel, Jitesh C. ;

Joshipura, Milind H. .

CHEMICAL, CIVIL AND MECHANICAL ENGINEERING TRACKS OF 3RD NIRMA UNIVERSITY INTERNATIONAL CONFERENCE ON ENGINEERING (NUICONE2012), 2013, 51 :403-408

[25] Vapor pressures and vaporization enthalpies of 1-nonadecanol. Isophytol, 2 Z- and 2 E-Phytol, and (2E,7R,11R) phytol by correlation gas chromatography [J].

Albinsaad, Mohammed ;

Scott, Nicole L. ;

Jim, James Chickos .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 153

[26] An examination of vaporization, fusion and sublimation enthalpies of tolazoline using correlation gas chromatography and differential scanning calorimetry [J].

Umnahanant, Patamaporn .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2019, 138 (01) :443-450

[27] An examination of vaporization, fusion and sublimation enthalpies of tolazoline using correlation gas chromatography and differential scanning calorimetry [J].

Patamaporn Umnahanant .

Journal of Thermal Analysis and Calorimetry, 2019, 138 :443-450

[28] Vapor pressure and vaporization enthalpy studies of the major components of ginger, α-zingiberene, β-sesquiphellandrene and (-) ar curcumene by correlation gas chromatography [J].

Siripoltangman, Natsanichapat ;

Chickos, James .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 138 :107-115

[29] Modeling vapor pressure of fatty acid and fatty acid methyl esters using cubic equations of state [J].

Joshipura, M. H. ;

Patel, R. J. .

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2015, 10 (02) :170-177

[30] DETERMINATION OF PHYSICOCHEMICAL PROPERTIES OF SOME FATTY-ACID METHYL-ESTERS BY GAS-LIQUID-CHROMATOGRAPHY [J].

HUSAIN, S ;

SARMA, PN ;

SWAMY, GYSK ;

DEVI, KS .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1993, 70 (02) :149-155

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