Densities and speeds of sound for binary mixtures of (1,3-dioxolane or 1,4-dioxane) with (2-methyl-1-propanol or 2-methyl-2-propanol) at the temperatures (298.15 and 313.15) K

被引:26
作者
Villares, A [1 ]
Martin, S [1 ]
Haro, M [1 ]
Giner, B [1 ]
Artigas, H [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, E-50009 Zaragoza, Spain
关键词
density; speed of sound; excess volume; excess isentropic compressibility coefficient; cyclic diether; butanol;
D O I
10.1016/j.jct.2004.07.015
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper reports densities and speeds of sound for the binary mixtures of (1,3-dioxolane or 1,4-dioxane) with (2-methyl-1-propanol or 2-methyl-2-propanol) at the temperatures (298.15 and 313.15) K. Excess volumes and excess isentropic compressibility coefficients have been calculated from experimental data and fitted by means of a Redlich-Kister type equation. The ERAS model has been used to calculate the excess volumes of the four systems at both temperatures. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1027 / 1036
页数:10
相关论文
共 35 条
[1]   ISENTROPIC COMPRESSIBILITY OF AN IDEAL TERNARY SOLUTION [J].
ACREE, WE .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1983, 28 (02) :215-216
[2]  
[Anonymous], 2002, HDB CHEM PHYS
[3]   THERMODYNAMICS OF THE TERNARY MIXTURE PROPAN-1-OL + TRIETHYLAMINE + NORMAL-HEPTANE - EXPERIMENTAL RESULTS AND ERAS-MODEL CALCULATIONS OF HE AND VE [J].
BENDER, M ;
HAUSER, J ;
HEINTZ, A .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1991, 95 (07) :801-811
[4]   THERMODYNAMICS OF 1-ALKANOL+N-ALKANE MIXTURES BASED ON PREDICTIONS OF THE ERAS MODEL [J].
BENDER, M ;
HEINTZ, A .
FLUID PHASE EQUILIBRIA, 1993, 89 (01) :197-215
[5]   EVALUATION OF EXCESS ISENTROPIC COMPRESSIBILITIES AND ISOCHORIC HEAT-CAPACITIES [J].
BENSON, GC ;
KIYOHARA, O .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1979, 11 (11) :1061-1064
[6]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[7]   Heat capacities, excess enthalpies, and volumes of mixtures containing cyclic ethers. 3. Binary systems {tetrahydrofuran, tetrahydropyran, 1,4-dioxane, or 1,3-dioxolane plus cyclohexane or toluene} [J].
Brocos, P ;
Calvo, E ;
Bravo, R ;
Pintos, M ;
Amigo, A .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (01) :67-72
[8]   Heat capacities, excess enthalpies, and volumes of mixtures containing cyclic ethers.: 5.: Binary systems {1,3-dioxolane+1-alkanols} [J].
Brocos, P ;
Calvo, E ;
Piñeiro, A ;
Bravo, R ;
Amigo, A ;
Roux, AH ;
Roux-Desgranges, G .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (06) :1341-1347
[9]   Excess molar volumes, and changes of isentropic compressibilities of ternary {acetone plus methanol plus (2-methyl-1-propanol, or 3-methyl-1-butanol)} at T=298.15 K [J].
Casás, LM ;
Marino, G ;
Iglesias, M ;
Orge, B ;
Tojo, J ;
Mosteiro, L .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2001, 33 (12) :1777-1789
[10]   MEASUREMENT, ANALYSIS, AND UTILITY OF EXCESS MOLAR - (PARTIAL-DERIVATIVEV/PARTIAL-DERIVATIVEP)S [J].
DOUHERET, G ;
DAVIS, MI .
CHEMICAL SOCIETY REVIEWS, 1993, 22 (01) :43-50