Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6):: a low valent gallium(I) carbene analogue

被引：308
作者：
Hardman, NJ [1 ]
Eichler, BE [1 ]
Power, PP [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 20期
关键词：
D O I：
10.1039/b005686n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction between solvent free Li{(NDippCMe)(2)CH} (Dipp = C6H3Pr2i-2,6), 'GaI' and potassium in toluene afforded Ga{(NDippCMe)(2)CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.
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页码：1991 / 1992
页数：2
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