An efficient Ni/Zn catalyst system for the chemical fixation of CO2 with epoxides

被引：0

作者：

Li, FW ^{[1
]}

Xiao, LF ^{[1
]}

Xia, CG ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

ACTA CHIMICA SINICA | 2004年 / 62卷 / 21期

关键词：

chemical fixation of carbon dioxide; cycloaddition; cyclic carbonate; TOF; cis-cyclohexene carbonate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of cyclic carbonates from epoxides and carbon dioxide catalyzed by NiCl2/bipy/Zn/TBAB catalyst system without any solvent was achieved in excellent selectivity and TOF at 1.5 MPa, 100 degreesC. Pure cis-cyclohexene carbonate was firstly obtained in this catalytic system.

引用

页码：2195 / 2199

页数：5

共 18 条

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