Electrochemical studies of metal carbonyl compounds

被引：40
作者：
Bond, AM [1 ]
Colton, R [1 ]
机构：
[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia
来源：
COORDINATION CHEMISTRY REVIEWS | 1997年 / 166卷
关键词：
D O I：
10.1016/S0010-8545(97)00022-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This article reviews our studies over some twenty years on the oxidative redox chemistry of Ise carbonyl derivatives of the group 6 and 7 transition metals. The necessity of coupling electrochemical and spectroscopic techniques is emphasized. Probably in all cases, the first oxidative step is a one-electron process and the subsequent chemistry of the system depends upon the stability and reactivity of 17e product. Isomerization is a common phenomenon, but when this is not possible disproportionation is often observed. (C) 1997 Elsevier Science S.A.
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页码：161 / 180
页数：20
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