A novel gold-catalyzed chemoselective reduction of α,β-unsaturated aldehydes using CO and H2O as the hydrogen source

被引：55
作者：
He, Lin [1 ]
Yu, Feng-Jiao [1 ]
Lou, Xia-Bing [1 ]
Cao, Yong [1 ]
He, He-Yong [1 ]
Fan, Kang-Nian [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 09期
关键词：
GAS SHIFT REACTION; LIQUID-PHASE HYDROGENATION; AEROBIC ALCOHOL OXIDATION; AU/CEO2; CATALYSTS; SELECTIVE HYDROGENATION; NITRO-COMPOUNDS; CROTONALDEHYDE; WATER; NANOPARTICLES; PROMOTION;
D O I：
10.1039/b922662a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chemoselective reduction of alpha,beta-unsaturated aldehydes in the presence of CO and H2O proceeds effectively over a ceria-supported gold catalyst system, providing a novel, efficient and clean approach to produce useful primary allyl alcohols with excellent activity and selectivity.
引用
收藏
页码：1553 / 1555
页数：3
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