A novel gold-catalyzed chemoselective reduction of α,β-unsaturated aldehydes using CO and H2O as the hydrogen source

被引：55

作者：

He, Lin ^{[1
]}

Yu, Feng-Jiao ^{[1
]}

Lou, Xia-Bing ^{[1
]}

Cao, Yong ^{[1
]}

He, He-Yong ^{[1
]}

Fan, Kang-Nian ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 09期

关键词：

GAS SHIFT REACTION; LIQUID-PHASE HYDROGENATION; AEROBIC ALCOHOL OXIDATION; AU/CEO2; CATALYSTS; SELECTIVE HYDROGENATION; NITRO-COMPOUNDS; CROTONALDEHYDE; WATER; NANOPARTICLES; PROMOTION;

D O I：

10.1039/b922662a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemoselective reduction of alpha,beta-unsaturated aldehydes in the presence of CO and H2O proceeds effectively over a ceria-supported gold catalyst system, providing a novel, efficient and clean approach to produce useful primary allyl alcohols with excellent activity and selectivity.

引用

页码：1553 / 1555

页数：3

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