One-pot synthesis of mesoporous spherical SnO2@graphene for high-sensitivity formaldehyde gas sensors

被引:54
作者
Chen, Shuai [1 ]
Qiao, Yan [1 ,4 ]
Huang, Jianlin [3 ]
Yao, Huanli [2 ]
Zhang, Yuanli [1 ]
Li, Yuan [1 ]
Du, Jianping [2 ]
Fan, Weibin [1 ,4 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, Analyt Instrumentat Ctr, Taiyuan 030001, Peoples R China
[2] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China
[3] S China Univ Technol, Sch Environm & Energy, New Energy Res Inst, Guangzhou 510006, Guangdong, Peoples R China
[4] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
基金
中国国家自然科学基金;
关键词
SENSING PROPERTIES; SNO2; NANOSTRUCTURES; LOW-TEMPERATURE; ZINC-OXIDE; NO2; GAS; GRAPHENE; NANOCOMPOSITES; PERFORMANCE; NANOWIRES; NANORODS;
D O I
10.1039/c6ra00857g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A versatile SnO2@graphene nanocomposite with a mesoporous structure was prepared by a facile and green solvothermal method. The nanocomposite exhibited high response to low-concentration HCHO (1 ppm) at low working temperature (120 degrees C). The response and recovery times are 1 s and 85 s for 1 ppm formaldehyde. There is an excellent linear relationship (R = 99.798%) between response and the concentration of HCHO in a large range (1-100 ppm).
引用
收藏
页码:25198 / 25202
页数:5
相关论文
共 30 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   Recent Advances in Tin Dioxide Materials: Some Developments in Thin Films, Nanowires, and Nanorods [J].
Chen, Zhiwen ;
Pan, Dengyu ;
Li, Zhen ;
Jiao, Zheng ;
Wu, Minghong ;
Shek, Chan-Hung ;
Wu, C. M. Lawrence ;
Lai, Joseph K. L. .
CHEMICAL REVIEWS, 2014, 114 (15) :7442-7486
[3]   Hydrogen bridges in crystal engineering: Interactions without borders [J].
Desiraju, GR .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :565-573
[4]   Size-controlled synthesis of SnO2 quantum dots and their gas-sensing performance [J].
Du, Jianping ;
Zhao, Ruihua ;
Xie, Yajuan ;
Li, Jinping .
APPLIED SURFACE SCIENCE, 2015, 346 :256-262
[5]   Self-Assembly of Grid like Zinc Oxide Lamellae for Chemical-Sensing Applications [J].
Du, Jianping ;
Zhao, Ruihua ;
Chen, Shuai ;
Wang, Heyan ;
Li, Jinping ;
Zhu, Zhenping .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (10) :5870-5878
[6]   Controllable synthesis of prism- and lamella-like ZnO and their gas sensing [J].
Du, Jianping ;
Yao, Huanli ;
Zhao, Ruihua ;
Wang, Heyan ;
Xie, Yajuan ;
Li, Jinping .
MATERIALS LETTERS, 2014, 136 :427-430
[7]   Ultrasensitive NH3 Gas Sensor from Polyaniline Nanograin Enchased TiO2 Fibers [J].
Gong, Jian ;
Li, Yinhua ;
Hu, Zeshan ;
Zhou, Zhengzhi ;
Deng, Yulin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (21) :9970-9974
[8]   Chemical and biological sensors based on metal oxide nanostructures [J].
Hahn, Yoon-Bong ;
Ahmad, Rafiq ;
Tripathy, Nirmalya .
CHEMICAL COMMUNICATIONS, 2012, 48 (84) :10369-10385
[9]   Fabrication of SnO2-SnO nanocomposites with p-n heterojunctions for the low-temperature sensing of NO2 gas [J].
Li, Lei ;
Zhang, Chunmei ;
Chen, Wei .
NANOSCALE, 2015, 7 (28) :12133-12142
[10]   Three-Dimensional Mesoporous Graphene Aerogel-Supported SnO2 Nanocrystals for High-Performance NO2 Gas Sensing at Low Temperature [J].
Li, Lei ;
He, Shuijian ;
Liu, Minmin ;
Zhang, Chunmei ;
Chen, Wei .
ANALYTICAL CHEMISTRY, 2015, 87 (03) :1638-1645