Synthesis and optical properties of naturally occurring fluorescent mineral, ferroan sphalerite, inspired (Fe,Zn)S nanoparticles

被引:5
作者
Boyle, Timothy J. [1 ]
Pratt, Harry D., III [1 ]
Hernandez-Sanchez, Bernadette A. [1 ]
Lambert, Timothy N. [1 ]
Headley, Thomas J. [1 ]
机构
[1] Sandia Natl Labs, Adv Mat Lab, Albuquerque, NM 87106 USA
基金
美国国家卫生研究院;
关键词
D O I
10.1007/s10853-006-1419-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Inspired by the naturally occurring fluorescent mineral, ferroan sphalerite, [(Fe, Zn) S] nanoparticles were synthesized by a three component reaction of [Fe(Mes)(2)](2) (Mes = mesityl or C6H2Me3-2,4,6), [Zn( Et)(ONep)(py)](2), and elemental S via both solution and solvothermal routes. The resultant nanoparticles are <= 3 nm and absorb at lambda(max) = 281 nm emitting a bright blue color (lambda(em) similar to 400 nm).
引用
收藏
页码:2792 / 2795
页数:4
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