Liquid polymorphism: water in nanoconfined and biological environments

被引：49

作者：

Stanley, H. E. ^{[1
,2
]}

Buldyrev, S. V. ^{[3
]}

Franzese, G. ^{[1
,2
,4
]}

Kumar, P. ^{[1
,2
]}

Mallamace, F. ^{[5
]}

Mazza, M. G. ^{[1
,2
]}

Stokely, K. ^{[1
,2
]}

Xu, L. ^{[6
]}

机构：

[1] Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USA

[2] Boston Univ, Dept Phys, Boston, MA 02215 USA

[3] Yeshiva Univ, Dept Phys, New York, NY 10033 USA

[4] Univ Barcelona, Dept Fis Fonamental, E-08028 Barcelona, Spain

[5] Univ Messina, Dipartimento Fis, I-98166 Messina, Italy

[6] Tohoku Univ, World Premier Int Res Ctr, Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 2010年 / 22卷 / 28期

基金：

美国国家科学基金会;

关键词：

STOKES-EINSTEIN RELATION; SUPERCOOLED CONFINED WATER; DYNAMIC CROSSOVER; CRITICAL-POINT; PHASE-DIAGRAM; MOLECULAR-DYNAMICS; UNUSUAL BEHAVIOR; DENSITY MINIMUM; HYDROGEN-BONDS; SLOW DYNAMICS;

D O I：

10.1088/0953-8984/22/28/284101

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We demonstrate some recent progress in understanding the anomalous behavior of liquid water, by combining information provided by recent experiments and simulations on water in bulk, nanoconfined, and biological environments. We interpret evidence from recent experiments designed to test the hypothesis that liquid water may display 'polymorphism' in that it can exist in two different phases-and discuss recent work on water's transport anomalies as well as the unusual behavior of water in biological environments. Finally, we will discuss how the general concept of liquid polymorphism may prove useful in understanding anomalies in other liquids, such as silicon, silica, and carbon, as well as metallic glasses which have in common that they are characterized by two characteristic length scales in their interactions.

引用

页数：12

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