Synthesis and crystal structure of [{Cd(hmbdc)(H2O)3}•2H2O]n

被引：0

作者：

Hu Yue-Hua

Wang Yan

Wang Zuo-Wei

Li Yi-Zhi

Zheng He-Gen ^{[1
]}

机构：

[1] Nanjing Univ, Coll Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Huangshan Univ, Huangshan 245041, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 26卷 / 04期

关键词：

Cd(II) complex; crystal structure; hydrogen bond; network structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel coordination polymer [{Cd(hmbdc)(H2O)(3)}center dot 2H(2)O](n) (hmbdc= 5-hydroxyisophthalic acid) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2(1)/c, with a 9.599(3), b = 18.699(5), c = 7.557(2) angstrom, beta = 108.198(4)degrees, V=1288.6(6) angstrom(3), Z = 4, M-r = 3 82.60, D-c 1.972 g/cm(3), F(000) = 760, mu = 1.740, the final R = 0.0555 and wR = 0.0995 for 1732 observed reflections with I > 2 sigma(I). The structural analysis shows that the intermolecular hydrogen bonds and pi-pi interactions result in a three-dimensional supramolecular framework.

引用

页码：423 / 426

页数：4

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