Effect of reactionary capable siloxane compatibilizer on the properties of blends of ethylene propylene diene and siloxane rubbers

被引:3
作者
Serenko, O. A. [1 ]
Pryakhina, T. A. [1 ]
Vasil'ev, V. G. [1 ]
Buzin, M., I [1 ]
Volkov, I. O. [1 ]
Kotov, V. M. [1 ]
Muzafarov, A. M. [1 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
ethylene propylene diene rubber; silicone rubber; compatibilizer; vulcanization; hydrosilylation; properties; POLYMER BLENDS; EPDM; MORPHOLOGY;
D O I
10.1007/s11172-021-3173-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polydimethyl(methylvinyl)siloxane with long-chain hydrocarbon fragments was synthesized at a sequence of chemical reactions. The resulting graft copolymer was used as a compatibilizer of ethylene propylene diene/siloxane rubbers blends of different compositions. It has been established that the introduction of reactive compatibilizer in a concentration not higher than 6 wt.% in the blend of rubbers allows to increase their compatibility due to co-vulcanization of graft copolymer with each of the components under the hydrosilylation conditions and, possibly, due to the formation of chemical bonds between rubber phases, which leads to an increase in the strength properties of the compositions.
引用
收藏
页码:960 / 966
页数:7
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