Li2B12H12•7NH3: a new ammine complex for ammonia storage or indirect hydrogen storage

被引：36

作者：

Huang, Zhenguo ^{[1
]}

Gallucci, Judith ^{[2
]}

Chen, Xuenian ^{[2
]}

Yisgedu, Teshome ^{[1
]}

Lingam, Hima Kumar ^{[1
]}

Shore, Sheldon G. ^{[2
]}

Zhao, Ji-Cheng ^{[1
]}

机构：

[1] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA

[2] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 14期

关键词：

DODECAHYDRO-CLOSO-DODECABORATE; DECOMPOSITION;

D O I：

10.1039/b923829h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new ammine complex, Li2B12H12 center dot 7NH(3), that can reversibly release all the NH3 at below 200 degrees C and reabsorb NH3 at room temperature and 0.5 bar was synthesized and investigated for reversible ammonia storage or indirect hydrogen storage.

引用

页码：2743 / 2745

页数：3

共 14 条

[1] Why the optimal ammonia synthesis catalyst is not the optimal ammonia decomposition catalyst [J].

Boisen, A ;

Dahl, S ;

Norskov, JK ;

Christensen, CH .

JOURNAL OF CATALYSIS, 2005, 230 (02) :309-312

[2] A new intermolecular interaction: Unconventional hydrogen bonds with element-hydride bonds as proton acceptor [J].

Crabtree, RH ;

Siegbahn, PEM ;

Eisenstein, O ;

Rheingold, AL .

ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (07) :348-354

[3]

Feibelman PJ, 2005, PHYS TODAY, V58, P13, DOI 10.1063/1.1996455

[4] FOURIER-TRANSFORM INFRARED SPECTROSCOPIC STUDY OF ADSORPTION AND DECOMPOSITION OF AMMONIA OVER MAGNESIUM-OXIDE [J].

KAGAMI, S ;

ONISHI, T ;

TAMARU, K .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :29-35

[5] Ammonia for hydrogen storage: challenges and opportunities [J].

Klerke, Asbjorn ;

Christensen, Claus Hviid ;

Norskov, Jens K. ;

Vegge, Tejs .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (20) :2304-2310

[6] Complex hydrides for hydrogen storage [J].

Orimo, Shin-ichi ;

Nakamori, Yuko ;

Eliseo, Jennifer R. ;

Zuettel, Andreas ;

Jensen, Craig M. .

CHEMICAL REVIEWS, 2007, 107 (10) :4111-4132

[7] The US Department of Energy's National Hydrogen Storage Project: Progress towards meeting hydrogen-powered vehicle requirements [J].

Satyapal, Sunita ;

Petrovic, John ;

Read, Carole ;

Thomas, George ;

Ordaz, Grace .

CATALYSIS TODAY, 2007, 120 (3-4) :246-256

[8]

SHELDRICK GM, 1998, SHELXTL 97 STRUCTURE

[9] Chemistry of closo-dodecaborate anion [B12H12]2-:: A review [J].

Sivaev, IB ;

Bregadze, VI ;

Sjöberg, S .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2002, 67 (06) :679-727

[10] Indirect, reversible high-density hydrogen storage in compact metal ammine salts [J].

Sorensen, Rasmus Z. ;

Hummelshoj, Jens S. ;

Klerke, Asbjorn ;

Reves, Jacob Birke ;

Vegge, Tejs ;

Norskov, Jens K. ;

Christensen, Claus H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (27) :8660-8668

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