Ceramics;
Chemical synthesis;
X-ray diffraction;
Piezoelectricity;
LEAD-FREE CERAMICS;
D O I:
10.1016/j.materresbull.2009.09.014
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
(1 - x) (K0.44Na0.52Li0.04)(Nb0.84Ta0.1Sb0.06)O-3 - x BiFeO3 (x = 0, 0.002, 0.004, 0.006, 0.008, 0.01) lead-free piezoelectric ceramics were prepared by the conventional ceramic processing. The compositional dependence of the phase structure and the electrical properties of the ceramics were studied. A morphotropic phase boundary between the orthorhombic and tetragonal phases was identified in the composition range of 0.004 < x < 0.006. The ceramics near the morphotropic phase boundary exhibit a strong compositional dependence and enhanced piezoelectric properties. The ceramics with 0.6 mol.% BiFeO3 exhibit good electrical properties (d(33) similar to 246 pC/N, k(p) similar to 43%, T-c similar to 285 degrees C, epsilon(r) similar to 1871, and tan delta similar to 1.96%). These results show that the (1 - x) (K0.44Na0.52Li0.04)(Nb0.84Ta0.1Sb0.06)O-3 - x BiFeO3 ceramic is a promising lead-free piezoelectric material for applications in different devices. (C) 2009 Elsevier Ltd. All rights reserved.
机构:
Nagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, JapanNagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, Japan
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Kim, Min-Soo
;
Lee, Dae-Su
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h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Lee, Dae-Su
;
Park, Eon-Cheol
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Park, Eon-Cheol
;
Jeong, Soon-Jong
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Jeong, Soon-Jong
;
Song, Jae-Sung
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
机构:
Nagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, JapanNagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, Japan
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Kim, Min-Soo
;
Lee, Dae-Su
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Lee, Dae-Su
;
Park, Eon-Cheol
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Park, Eon-Cheol
;
Jeong, Soon-Jong
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea
Jeong, Soon-Jong
;
Song, Jae-Sung
论文数: 0引用数: 0
h-index: 0
机构:
Korea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South KoreaKorea Electrotechnol Res Inst, Elect & Magnet Devices Grp, Chang Won 641120, South Korea