Morphology studies of poly(ethylene terephthalate)/silica nanocomposites

被引:5
作者
Liu, Wentao [1 ]
Wu, Linlin [1 ]
Tian, Xingyou [2 ]
Zheng, Jin [3 ]
Cui, Ping [2 ]
He, Suqin [1 ]
Zhu, Chengshen [1 ]
机构
[1] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450052, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
[3] Zhongyuan Inst Technol, Dept Text Engn, Zhengzhou 450007, Peoples R China
关键词
Poly(ethylene terephthalate); Silica; AFM; SEM; Morphology; LAYERED SILICATE NANOCOMPOSITES; ENERGY-DISSIPATION; BEHAVIOR;
D O I
10.1007/s00289-009-0235-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(ethylene terephthalate)/silica nanocomposites have been prepared through in situ polymerization. The morphology was investigated by atomic force microscopy in the tapping mode and scanning electron microscope. The interface morphological structure of the poly(ethylene terephthalate)/silica nanocomposites strongly depends on the ratio of silica in the matrix. When silica weight fraction is lower than 3 wt%, the system consists of aggregated silica particles dispersed in the organic matrix; beyond this concentration, the structure is co-continuous with that of the organic matrix. Surface of poly(ethylene terephthalate) was smooth; while nanocomposites were rough, there are good interfacial adhesion and compatibility between the polymer matrix and the nanofillers.
引用
收藏
页码:133 / 143
页数:11
相关论文
共 34 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]   Interactions of nanoscopic particles with phase-separating polymeric mixtures [J].
Balazs, AC .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1999, 4 (06) :443-448
[3]   Molecular dynamics simulation study of norbornene-POSS polymers [J].
Bharadwaj, RK ;
Berry, RJ ;
Farmer, BL .
POLYMER, 2000, 41 (19) :7209-7221
[4]   The effect of filler surface modification and processing conditions on distribution behaviour of silica nanofillers in polyesters [J].
Bula, Karol ;
Jesionowski, Teofil ;
Krysztafkiewicz, Andrzej ;
Janik, Jolanta .
COLLOID AND POLYMER SCIENCE, 2007, 285 (11) :1267-1273
[5]   Synthesis and optical properties of poly(BPDA-ODA)/silica hybrid thin films [J].
Chang, CC ;
Wei, KH ;
Chang, YL ;
Chen, WC .
JOURNAL OF POLYMER RESEARCH-TAIWAN, 2003, 10 (01) :1-6
[6]   Processing and morphological development of montmorillonite epoxy nanocomposites [J].
Chen, CG ;
Curliss, D .
NANOTECHNOLOGY, 2003, 14 (06) :643-648
[7]   Synthesis and characterization of poly(methyl methacrylate)-silica hybrid optical thin films [J].
Chen, WC ;
Lee, SJ .
POLYMER JOURNAL, 2000, 32 (01) :67-72
[8]   Energy dissipation in tapping-mode atomic force microscopy [J].
Cleveland, JP ;
Anczykowski, B ;
Schmid, AE ;
Elings, VB .
APPLIED PHYSICS LETTERS, 1998, 72 (20) :2613-2615
[9]   Structural development during deformation of polyurethane containing polyhedral oligomeric silsesquioxanes (POSS) molecules [J].
Fu, BX ;
Hsiao, BS ;
Pagola, S ;
Stephens, P ;
White, H ;
Rafailovich, M ;
Sokolov, J ;
Mather, PT ;
Jeon, HG ;
Phillips, S ;
Lichtenhan, J ;
Schwab, J .
POLYMER, 2001, 42 (02) :599-611
[10]  
Giannelis EP, 1998, APPL ORGANOMET CHEM, V12, P675, DOI 10.1002/(SICI)1099-0739(199810/11)12:10/11<675::AID-AOC779>3.0.CO